Molecular catalysts for water oxidation

JD Blakemore, RH Crabtree, GW Brudvig - Chemical Reviews, 2015 - ACS Publications
The development of technologies for the production of chemical fuels or useful compounds
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …

[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation

MD Karkas, O Verho, EV Johnston… - Chemical reviews, 2014 - ACS Publications
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …

Low‐coordinate iridium oxide confined on graphitic carbon nitride for highly efficient oxygen evolution

J Chen, P Cui, G Zhao, K Rui, M Lao… - Angewandte Chemie …, 2019 - Wiley Online Library
Highly active and durable electrocatalysts for the oxygen evolution reaction (OER) is greatly
desired. Iridium oxide/graphitic carbon nitride (IrO2/GCN) heterostructures are designed with …

Investigation of photo-electrochemical response of iron oxide/mixed-phase titanium oxide heterojunction toward possible solar energy conversion

M Khosravi, H Feizi, B Haghighi… - International Journal of …, 2021 - Elsevier
Photocatalysts are part of key strategies to enable green fuel. Photocatalysis and water
splitting could be a promising solution to challenges associated with the intermittent nature …

Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis?

V Artero, M Fontecave - Chemical Society Reviews, 2013 - pubs.rsc.org
Catalysis is a key enabling technology for solar fuel generation. A number of catalytic
systems, either molecular/homogeneous or solid/heterogeneous, have been developed …

Iridium-based complexes for water oxidation

JM Thomsen, DL Huang, RH Crabtree… - Dalton …, 2015 - pubs.rsc.org
Organometallic Ir precatalysts have been found to yield homogeneous Ir-based water-
oxidation catalysts (WOCs) with very high activity. The Cp* Ir catalyst series can operate …

A leap forward in iridium–NHC catalysis: new horizons and mechanistic insights

M Iglesias, LA Oro - Chemical Society Reviews, 2018 - pubs.rsc.org
This review summarises the most recent advances in Ir–NHC catalysis while revisiting all the
classical reactions in which this type of catalyst has proved to be active. The influence of the …

HERFD-XAS and valence-to-core-XES: new tools to push the limits in research with hard X-rays?

M Bauer - Physical Chemistry Chemical Physics, 2014 - pubs.rsc.org
In this perspective, the HERFD-XANES (high energy resolution fluorescence detected X-ray
absorption near edge structure) and Kβ2, 5-or V2C-XES (valence-to-core X-ray emission …

The importance of identifying the true catalyst when using Randles-Sevcik equation to calculate turnover frequency

Z Abdi, M Vandichel, AS Sologubenko… - International Journal of …, 2021 - Elsevier
Water splitting will become important to store excess renewable electrical energy into
hydrogen. Although the oxygen-evolution reaction (OER) by water oxidation is a critical …

Water splitting by a pentanuclear iron complex

S Mehrabani, R Bikas, Z Zand, Y Mousazade… - International Journal of …, 2020 - Elsevier
Water splitting toward hydrogen and oxygen production is a promising way to store energy.
Oxygen-evolution reaction (OER) provides electron for hydrogen production. However, OER …