Frontal polymerizations: from chemical perspectives to macroscopic properties and applications
The synthesis and processing of most thermoplastics and thermoset polymeric materials rely
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …
Polymers as Aerospace Structural Components: How to Reach Sustainability?
The aerospace industry has been benefiting from the utilization of polymer materials since
fiber‐reinforced polymer composites (FRPC) offer high performances at low densities …
fiber‐reinforced polymer composites (FRPC) offer high performances at low densities …
Kinetic and Chemical Effects of Clays and Other Fillers in the Preparation of Epoxy–Vinyl Ether Composites Using Radical-Induced Cationic Frontal Polymerization
BR Groce, EE Lane, DP Gary, DT Ngo… - … Applied Materials & …, 2023 - ACS Publications
Addition of fillers to formulations can generate composites with improved mechanical
properties and lower the overall cost through a reduction of chemicals needed. In this study …
properties and lower the overall cost through a reduction of chemicals needed. In this study …
Controlled patterning of crystalline domains by frontal polymerization
Materials with hierarchical architectures that combine soft and hard material domains with
coalesced interfaces possess superior properties compared with their homogeneous …
coalesced interfaces possess superior properties compared with their homogeneous …
Frontal Polymerization of Stereoisomers: Distinct Microstructures and Properties in Endo- and Exo-Dicyclopentadiene Thermosets
This study explores the relationship between monomer stereochemistry and the materials
properties of thermosets generated by frontal ring-opening metathesis polymerization …
properties of thermosets generated by frontal ring-opening metathesis polymerization …
Unraveling Reactivity Differences: Room-Temperature Ring-Opening Metathesis Polymerization (ROMP) versus Frontal ROMP
In this study, we explore the distinct reactivity patterns between frontal ring-opening
metathesis polymerization (FROMP) and room-temperature solventless ring-opening …
metathesis polymerization (FROMP) and room-temperature solventless ring-opening …
Synergistic dual-cure reactions for the fabrication of thermosets by chemical heating
Large composite structures, such as those used in wind energy applications, rely on the bulk
polymerization of thermosets on an impressively large scale. To accomplish this, traditional …
polymerization of thermosets on an impressively large scale. To accomplish this, traditional …
Using Data Science Tools to Reveal and Understand Subtle Relationships of Inhibitor Structure in Frontal Ring-Opening Metathesis Polymerization
TP McFadden, RB Cope, R Muhlestein… - Journal of the …, 2024 - ACS Publications
The rate of frontal ring-opening metathesis polymerization (FROMP) using the Grubbs
generation II catalyst is impacted by both the concentration and choice of monomers and …
generation II catalyst is impacted by both the concentration and choice of monomers and …
Achieving performance‐advantaged polydicyclopentadiene via sequential ring‐opening metathesis polymerization and radical reaction
Q Zhan, F Huangfu, P Yang - Polymer International, 2024 - Wiley Online Library
Herein, we develop an approach to achieve performance‐advantaged
polydicyclopentadiene (PDCPD) via sequential ring‐opening metathesis polymerization …
polydicyclopentadiene (PDCPD) via sequential ring‐opening metathesis polymerization …
[HTML][HTML] Bubble-Free Frontal Polymerization of Acrylates via Redox-Initiated Free Radical Polymerization
M Ziaee, M Yourdkhani - Polymers, 2024 - mdpi.com
Thermal frontal polymerization (FP) of acrylate monomers mixed with conventional peroxide
initiators leads to significant bubble formation at the polymerizing front, limiting their practical …
initiators leads to significant bubble formation at the polymerizing front, limiting their practical …