The catalytic asymmetric construction of C sp 3–C sp 3 bonds remains one of the foremost
challenges in organic synthesis. Metal-catalysed cross-electrophile couplings (XECs) have …

Tertiary nitroalkanes and the corresponding α-tertiary amines represent important motifs in
bioactive molecules and natural products. The C-alkylation of secondary nitroalkanes with …

Nitro compounds serve as valuable intermediates for pharmaceuticals, agrochemicals, dyes,
and polymers. In recent years, radical nitration using tert-butyl nitrite (t-BuONO) has attracted …

The photosynthetic preparation of N‐aryl‐and N‐alkyl‐bearing carbazoles utilizes
continuous flow, visible light, and an in situ formed Cu‐based sensitizer (see picture). The …

Nitroalkanes, mainly the primary ones, are the key starting materials for the synthesis of a
large variety of important targets. However, in spite of their strategic synthetic importance …

An operationally simple and metal-free protocol for geometrically inaccessible C5–H
halogenation of a range of 8-substituted quinoline derivatives has been established. The …

The preparation of tertiary nitroalkanes via the nickel-catalyzed alkylation of secondary
nitroalkanes using aliphatic iodides is reported. Previously, catalytic access to this important …

A catalytic intermolecular amination of nonactivated tertiary C (sp3)–H bonds (BDE of 96
kcal· mol–1) is reported for substrates displaying an activated benzylic site (BDE of 85 kcal …

A quinone-mediated general synthetic platform for the construction of primary α-tertiary
amines from abundant primary α-branched amine starting materials is described. This …

Metal-free carbonitration of alkenes using K 2 S 2 O 8 - Chemical Communications (RSC
Publishing) DOI:10.1039/C3CC47287F Royal Society of Chemistry View PDF VersionPrevious …