The role of water in Earth's mantle

E Ohtani - National Science Review, 2020 - academic.oup.com
Geophysical observations suggest that the transition zone is wet locally. Continental and
oceanic sediment components together with the basaltic and peridotitic components might …

Stability of hydrous silicate at high pressures and water transport to the deep lower mantle

M Nishi, T Irifune, J Tsuchiya, Y Tange, Y Nishihara… - Nature …, 2014 - nature.com
The presence of water strongly influences the structure, composition and dynamics of the
Earth's deep mantle,,,. Hydrous magnesium-rich silicates play an important role in …

The role of hydrogen bonds in hydrous minerals stable at lower mantle pressure conditions

J Tsuchiya, EC Thompson - Progress in Earth and Planetary Science, 2022 - Springer
Over the past few decades, hydrous minerals were thought to be absent in the lower mantle,
due to their instability at high-pressure conditions. Recently, however, hydrous phases …

Hydrous minerals and the storage of water in the deep mantle

E Ohtani - Chemical Geology, 2015 - Elsevier
Water is transported into the deep mantle via hydrous minerals in subducting slabs. During
subduction, a series of minerals in these slabs such as serpentine or chlorite, Mg–sursassite …

Direct observation of symmetrization of hydrogen bond in δ-AlOOH under mantle conditions using neutron diffraction

A Sano-Furukawa, T Hattori, K Komatsu, H Kagi… - Scientific Reports, 2018 - nature.com
At ambient pressure, the hydrogen bond in materials such as ice, hydrates, and hydrous
minerals that compose the Earth and icy planets generally takes an asymmetric OH··· O …

First principles prediction of a new high‐pressure phase of dense hydrous magnesium silicates in the lower mantle

J Tsuchiya - Geophysical Research Letters, 2013 - Wiley Online Library
First principles calculations have shown that the high‐pressure phase transition of phase D
MgSi2O6H2 to the new high‐pressure hydrous phase MgSiO4H2 plus stishovite occurs at …

Change in compressibility of δ-AlOOH and δ-AlOOD at high pressure: A study of isotope effect and hydrogen-bond symmetrization

A Sano-Furukawa, H Kagi, T Nagai… - American …, 2009 - pubs.geoscienceworld.org
The compression behaviors of δ-AlOOH and δ-AlOOD were investigated under quasi-
hydrostatic conditions at pressures up to 63.5 and 34.9 GPa, respectively, using results from …

Phase transitions in Ɛ-FeOOH at high pressure and ambient temperature

EC Thompson, AH Davis, NM Brauser, Z Liu… - American …, 2020 - degruyter.com
Constraining the accommodation, distribution, and circulation of hydrogen in the Earth's
interior is vital to our broader understanding of the deep Earth due to the significant …

Compression of ice to 126 GPa and implications for hydrogen-bond symmetrization: Synchrotron x-ray diffraction measurements and density-functional …

E Sugimura, T Iitaka, K Hirose, K Kawamura… - Physical Review B …, 2008 - APS
We examined the volume compression and phase transformations of H 2 O ice by a
combination of synchrotron x-ray diffraction measurements and density-functional …

Structure and elasticity of serpentine at high-pressure

M Mookherjee, L Stixrude - Earth and Planetary Science Letters, 2009 - Elsevier
Serpentines occur in the subduction zone settings, both along the slab and within the mantle
wedge, they are candidates for transporting water in to the deep earth. Their presence is …