The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Non‐noble metal catalysts based on pincer type compounds are of special interest for
organometallic chemistry and organic synthesis. Next to iron and manganese, currently …

The economical and sustainable nature of base metals has recently inspired extensive
investigations on the development of iron and cobalt catalysts for alkene and alkyne …

Transition-metal-catalyzed alkene hydrosilylation is one of the most important homogeneous
catalytic reactions, and the development of methods that use base metals, especially iron, as …

This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

A highly regio-and enantioselective cobalt-catalyzed hydroboration/hydrogenation of
internal alkynes with HBpin and a hydrogen balloon in one pot was developed. A new type …

Base metal catalysis offers an alternative to reactions, which were once dominated by
precious metals in hydrofunctionalization reactions. This review article details the …

We report the design and synthesis of cobalt complexes of L2X-type ligands for olefin
hydroboration guided by the consideration of catalyst stability. Among the series of PCP …