Recent advances in the synthesis and reactivity of quinoxaline

G Yashwantrao, S Saha - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Quinoxaline has become a subject of extensive research due to its emergence as an
important chemical moiety, demonstrating a wide range of physicochemical and biological …

Cobalt-catalyzed hydrogenations via olefin cobaltate and hydride intermediates

S Sandl, TM Maier, NP van Leest, S Kröncke… - ACS …, 2019 - ACS Publications
Redox noninnocent ligands are a promising tool to moderate electron transfer processes
within base-metal catalysts. This report introduces bis (imino) acenaphthene (BIAN) …

Cobalt-catalyzed ammonia borane dehydrogenation: Mechanistic insight and isolation of a cobalt hydride-amidoborane complex

JW Nugent, M García-Melchor, AR Fout - Organometallics, 2020 - ACS Publications
A Co (I) complex featuring the electron-rich monoanionic bis (carbene) aryl pincer ligand
(MesCCC)(MesCCC= bis (2, 4, 6-trimethylphenyl-benzimidazol-2-ylidene) …

Liquid-phase hydrogenation of nitriles to amines facilitated by a Co (II)/Zn (0) pair: a ligand-free catalytic protocol

D Timelthaler, C Topf - The Journal of Organic Chemistry, 2019 - ACS Publications
The given report introduces a simple and user-friendly in situ method for the production of
catalytically active cobalt particles. The approach circumvents the use of air-and moisture …

Diethylsilane as a Powerful Reagent in Au Nanoparticle‐Catalyzed Reductive Transformations

A Louka, M Kidonakis, I Saridakis… - European Journal of …, 2020 - Wiley Online Library
Diethylsilane (Et2SiH2), a simple and readily available dihydrosilane, that exhibits superior
reactivity, as compared to monohydrosilanes, in a series of reductive transformations …