Recent advances in the synthesis of luminescent tetra-coordinated boron compounds

AC Murali, P Nayak, K Venkatasubbaiah - Dalton Transactions, 2022 - pubs.rsc.org
Tetra-coordinated boron compounds offer a plethora of luminescent materials. Different
chelation around the boron center (O, O-, N, C-, N, O-, and N, N-) has been explored to tune …

Photostable small-molecule NIR-II fluorescent scaffolds that cross the blood–brain barrier for noninvasive brain imaging

S Wang, H Shi, L Wang, A Loredo… - Journal of the …, 2022 - ACS Publications
The second near-infrared (NIR-II, 1000–1700 nm) fluorescent probes have significant
advantages over visible or NIR-I (600–900 nm) imaging for both depth of penetration and …

Boron difluoride hydrazone (BODIHY) complexes: A new class of fluorescent molecular rotors

AN Bismillah, I Aprahamian - Journal of Physical Organic …, 2023 - Wiley Online Library
Fluorescent dyes exhibiting luminescence in the solid state are crucial for the development
of efficient solid‐state lighting devices. Most fluorophores though do not emit in the solid …

Advancements in boron difluoride formazanate dyes for biological imaging

S Yang, K Lu, H Xiao - Current opinion in chemical biology, 2024 - Elsevier
In the past decade, boron difluoride formazanate dyes have gained considerable attention
due to their redox activity, high absorption and emission intensities, chemical stability across …

Reengineering of Donor–Acceptor–Donor Structured Near-Infrared II Aggregation-Induced Emission Luminogens for Starving-Photothermal Antitumor and Inhibition …

M Yang, S Wang, X Ou, J Ni, S Segawa, J Sun, F Xu… - ACS …, 2024 - ACS Publications
Electron acceptor possessing strong electron-withdrawing ability and exceptional stability is
crucial for developing donor–acceptor–donor (DAD) structured aggregation-induced …

Blending the optical and redox properties of oligoynes and boron difluoride formazanates

JS Dhindsa, EL Cotterill, FL Buguis… - Angewandte …, 2022 - Wiley Online Library
Oligoynes and polyynes are 1D chains of conjugated sp‐hybridized carbon atoms
consisting of alternating single and triple bonds. Their stability rapidly decreases with …

Band gap engineering in acceptor-donor-acceptor boron difluoride formazanates

JS Dhindsa, FL Buguis, M Anghel… - The Journal of Organic …, 2021 - ACS Publications
π-Conjugated molecules with acceptor-donor-acceptor (ADA) electronic structures make up
an important class of materials due to their tunable optoelectronic properties and …

Synthesis and bio-activity of complex azo compounds: A review on formazans and its complexes

N Singh, HS Sohal, M Verma, R Sharma… - Main Group …, 2024 - content.iospress.com
Formazans are well-known complexing agents and form highly stable complexes with verity
of metals that are useful for number of pharmaceutical applications. The activity profile of …

Dyads and Triads of Boron Difluoride Formazanate and Boron Difluoride Dipyrromethene Dyes

FL Buguis, NSY Hsu, SA Sirohey… - … A European Journal, 2023 - Wiley Online Library
Dye‐dye conjugates have attracted significant interest for their utility in applications such as
bioimaging, theranostics, and light‐harvesting. Many classes of organic dyes have been …

Dual Emission, Aggregation, and Redox Properties of Boron Difluoride Hydrazones Functionalized with Triphenylamines

D Cappello, FL Buguis, PD Boyle… - ChemPhotoChem, 2022 - Wiley Online Library
Abstract π‐Conjugated molecular materials often exhibit interesting photoluminescence,
redox, and optoelectronic properties that grant them utility as light‐harvesting materials in …