Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Complexes of metals with N-heterocyclic carbene ligands (M/NHC) are typically considered
the systems of choice in homogeneous catalysis due to their stable metal–ligand framework …

Iron is the most abundant transition metal in Earth, s crust; it is relatively inexpensive, not
very toxic, and environmentally benign. 1 Undoubtedly, due to the involvement in a multitude …

Single-molecule magnets (SMMs) display slow relaxation of the magnetization, purely of
molecular origin, in the absence of an applied magnetic field. This review summarizes the …

Complexes bearing protic N-heterocyclic carbenes (protic NHCs, pNHCs), defined as cyclic
carbenes stabilized by two heteroatoms including at least one NH group, have been less …

N-Heterocyclic carbenes (NHCs) are nowadays ubiquitous and indispensable as ancillary
ligands in organotransition metal chemistry, with an enormous variety of NHC types known …

The development of homogeneous iron catalysts has been a prolific research field in recent
years. Many catalytic reactions are no longer limited to noble metals. The use of N …

N-Heterocyclic carbenes (NHCs) are widely used ligands and reagents in modern inorganic
synthesis as well as in homogeneous catalysis and organocatalysis. However, NHCs are …

Alternating current magnetic investigations on the trigonal-planar high-spin Co2+ complexes
[Li (15-crown-5)][Co {N (SiMe3) 2} 3],[Co {N (SiMe3) 2} 2 (THF)](THF= tetrahydrofuran), and …