Metal carbonyl clusters of groups 8–10: synthesis and catalysis

C Cesari, JH Shon, S Zacchini… - Chemical Society Reviews, 2021 - pubs.rsc.org
In this review article, we discuss advances in the chemistry of metal carbonyl clusters
(MCCs) spanning the last three decades, with an emphasis on the more recent reports and …

Platinum carbonyl clusters chemistry: four decades of challenging nanoscience

I Ciabatti, C Femoni, MC Iapalucci, G Longoni… - Journal of Cluster …, 2014 - Springer
The state of art of the chemical, spectroscopic and structural characterization of platinum
carbonyl clusters is reviewed. We begin by enlightening the fundamental contribution given …

Systematic investigation of the antiproliferative activity of a series of ruthenium terpyridine complexes

J Karges, O Blacque, M Jakubaszek, B Goud… - Journal of inorganic …, 2019 - Elsevier
Due to acquired resistance or limitations of the currently approved drugs against cancer,
there is an urgent need for the development of new classes of compounds. Among others …

Pt and Pt/Sn carbonyl clusters as precursors for the synthesis of supported metal catalysts for the base-free oxidation of HMF

D Bonincontro, A Lolli, A Storione, A Gasparotto… - Applied Catalysis A …, 2019 - Elsevier
In the present work, Pt and Pt/Sn nanoparticles (NPs), synthesized from carbonyl cluster
precursors were deposited on TiO 2 and the resulting materials were tested as catalysts in …

Using metal carbonyl clusters to develop a molecular approach towards metal nanoparticles

S Zacchini - European Journal of Inorganic Chemistry, 2011 - Wiley Online Library
This microreview aims at presenting a personal perspective on the possible contributions of
molecular metal carbonyl clusters (MCCs) to a better understanding and development of …

Recent progress in the chemistry of anionic groups 6–8 carbonyl chalcogenide clusters

M Shieh, CY Miu, YY Chu, CN Lin - Coordination Chemistry Reviews, 2012 - Elsevier
Main-group element-bridged transition metal carbonyl complexes represent an important
field in contemporary chemistry. This review will focus on the recent development of groups …

When Crystals Go Nano–The Role of Advanced X‐ray Total Scattering Methods in Nanotechnology

F Bertolotti, D Moscheni, A Guagliardi… - European Journal of …, 2018 - Wiley Online Library
Controlling the stoichiometry, structure, defects, size, and shape of engineered
nanomaterials (in the forms of powders, colloids, and thin films) is a fundamental issue in …

Metal carbonyl cluster-based coordination polymers: diverse syntheses, versatile network structures, and special properties

M Shieh, YH Liu, YH Li, RY Lin - CrystEngComm, 2019 - pubs.rsc.org
The incorporation of metal carbonyl clusters into the backbone of coordination polymers
represents an important field in contemporary chemistry. The development of metal carbonyl …

Continuous flow synthesis of atom-precise platinum clusters

C Schmitt, N Da Roit, M Neumaier, CB Maliakkal… - Nanoscale …, 2024 - pubs.rsc.org
Subnanometer clusters with precise atom numbers hold immense potential for applications
in catalysis, as single atoms can significantly impact catalytic properties. Typically, inorganic …

Syntheses, Structures, and Electrochemistry of the Defective ccp [Pt33(CO)38]2– and the bcc [Pt40(CO)40]6– Molecular Nanoclusters

E Cattabriga, I Ciabatti, C Femoni, T Funaioli… - Inorganic …, 2016 - ACS Publications
The molecular [Pt33 (CO) 38] 2–nanocluster was obtained from the thermal decomposition
of Na2 [Pt15 (CO) 30] in methanol. The reaction of [Pt19 (CO) 22] 4–with acids (1–2 equiv) …