Abstract Poly (cyclopentene carbonate)(PCPC) produced by copolymerization of CO2 and
cyclopentene oxide (CPO) is a promising but challenging chemical recyclable polymer that …

Two borane-functionalized bidentate phosphine ligands that vary in tether length have been
prepared to examine cooperative metal–substrate interactions. Ni (0) complexes react with …

The role of the counterion in metal-catalyzed reactions can be crucial as this often-
unconsidered component of the catalyst can modify the performance of the catalyst and …

The phosphine-borane i Pr2P (o-C6H4) BFxyl2 (Fxyl= 3, 5-(F3C) 2C6H3) 1-Fxyl was found
to promote the reductive elimination of ethane from [AuMe2 (μ-Cl)] 2. Nuclear magnetic …

This perspective provides an entry-level conversation concerning base metal catalysis as a
green and sustainable solution in industrial and academic contexts. We establish a …

The use of metal catalysts to accelerate an organic transformation has proven indispensable
for access to structural motifs having applications across medicinal, polymer, materials …

Metal‐ligand cooperation has emerged as a versatile tool for substrate activation in
chemical reactivity. Herein, we provide the synthesis and characterization of a monoboranyl …

Phosphine-boranes do not promote oxidative addition of acyl chlorides to gold, but the
phosphine-borane gold triflimide complex [iPr2P (o-C6H4) BCy2] AuNTf2 was found to …

The development of methodologies for regioselective C–H functionalization of N-
heterocycles has seen sustained growth over the last two decades. Cooperative reactivity …

Diphosphines have taken on a dominant role as supporting ligands in transition-metal
chemistry. Here, we describe complexes of the type [Cp* Fe (diphosphine)(X)](X= Cl, H) …