Transition-metal-catalyzed decarbonylation via carbon–carbon bond cleavage is an
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …

Much progress has been made in the development of methods to both create compounds
that contain C− F bonds and to functionalize C− F bonds. As such, C− F bonds are becoming …

Abstract The Suzuki–Miyaura cross-coupling of organoboron nucleophiles with aryl halide
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …

In this Review, we summarize the current state of the art in late‐transition‐metal‐catalyzed
reactions of acyl fluorides, covering both their synthesis and further transformations. In …

This Article describes the development of a base-free, nickel-catalyzed decarbonylative
coupling of carboxylic acid fluorides with diboron reagents to selectively afford aryl boronate …

This Article describes the development of a decarbonylative Pd-catalyzed aryl–fluoroalkyl
bond-forming reaction that couples fluoroalkylcarboxylic acid-derived electrophiles [RFC (O) …

Several recent reports outlined the singular reactivity of acid fluorides as excellent
electrophiles in transition‐metal catalysis. These species undergo oxidative addition of the …

The expansion of chemical space associated with ubiquitous motifs is key to unleash new
properties and functions. In this context, alkynamides, prevalent in numerous drugs and …

A fast and simple method for deoxyfluorination of carboxylic acids is presented. The protocol
employs commodity chemicals (PPh3, NBS, fluoride), affording products in excellent yields …

We describe a novel reagent system to obtain acyl fluorides directly from three different
functional group precursors: carboxylic acids, aldehydes, or alcohols. The transformation is …