IR spectroscopic characterization of 3d transition metal carbene cations, FeCH 2+ and CoCH 2+: periodic trends and a challenge for DFT approaches

FJ Wensink, CE Smink, PB Armentrout… - Physical Chemistry …, 2024 - pubs.rsc.org
A combination of IR multiple-photon dissociation (IRMPD) action spectroscopy and quantum
chemical calculations was employed to investigate the [M, C, 2H]+(M= Fe and Co) species …

Infrared Spectroscopic Characterization of Early 4d Transition Metal Carbene Cations, ZrCH2+ and NbCH2+

PB Armentrout, OV Lushchikova… - The Journal of …, 2024 - ACS Publications
IR multiple-photon dissociation (IRMPD) action spectroscopy is combined with quantum
chemical calculations to examine the [M, C, 2H]+ species for the early 4d metals, M= Zr and …

[PDF][PDF] IR spectroscopic characterization of 3d transition metal carbene cations, FeCH2 and CoCH2: Periodic Trends and A Challenge for DFT approaches

FJ Wensink, CE Smink, PB Armentrout, JM Bakker - scholar.archive.org
ABSTRACT A combination of IR multiple-photon dissociation (IRMPD) action spectroscopy
and quantum chemical calculations was employed to investigate the [M, C, 2H]+(M= Fe and …