Intramolecularly hydrogen-bonded peptide conformation

C Toniolo, E Benedetti - Critical Reviews in Biochemistry, 1980 - Taylor & Francis
The object of this article is to review the developments in the field of intramolecularly H-
bonded extended and folded conformations in linear and cyclic peptide molecules. The …

Circular dichroism studies of distorted α-helices, twisted β-sheets, and β-turns

MC Manning, M Illangasekare, RW Woody - Biophysical chemistry, 1988 - Elsevier
Theoretical models for calculating the circular dichroism (CD) of biopolymers have been
constructed which allow the evaluation of the effects of geometric distortions within regular …

Metal− peptide frameworks (MPFs):“Bioinspired” metal organic frameworks

A Mantion, L Massüger, P Rabu, C Palivan… - Journal of the …, 2008 - ACS Publications
Chiral metal-organic frameworks (MOFs) have attracted a growing interest for their potential
use in energy technologies, asymmetric catalysis, chiral separation, and on a more basic …

Comparison of the effect of five guest residues on the. beta.-sheet conformation of host (L-val) n oligopeptides

V Moretto, M Crisma, GM Bonora, C Toniolo… - …, 1989 - ACS Publications
Thesynthesis, characterization, and IR absorption, NMR, and CD properties of (L-Val)„host
tetra-, penta-, and hexapeptides containing an L-Ile, L-Ala, D-Val, L-Pro, or Aib guest residue …

The importance of being Aib. Aggregation and self‐assembly studies on conformationally constrained oligopeptides

M Venanzi, E Gatto, F Formaggio… - Journal of Peptide …, 2017 - Wiley Online Library
The role of the conformationally constrained α‐aminoisobutyric acid (Aib) residue in the
aggregation and self‐assembly properties of oligopeptides is discussed, critically reviewing …

Synthetic enzymes—4: Highly enantioselective epoxidation by means of polyaminoacids in a triphase system: Influence of structural variations within the catalysts

S Colonna, H Molinari, S Banfi, S Juliá, J Masana… - Tetrahedron, 1983 - Elsevier
The asymmetric epoxidation of chalcone and other electron-poor olefins in a triphase system
(water-organic solvent-polyaminoacid) affords optically active oxiranes. The influence of the …

Effect of Nα-Acyl Chain Length on the Membrane-Modifying Properties of Synthetic Analogs of the Lipopeptaibol Trichogin GA IV

C Toniolo, M Crisma, F Formaggio… - Journal of the …, 1996 - ACS Publications
Trichogin GA IV, an 11-residue lipopeptaibol blocked at the N-terminus by an n-octanoyl
group and at the C-terminus by a 1, 2-amino alcohol (l-leucinol), extracted from the fungus …

Orientation and immersion depth of a helical lipopeptaibol in membranes using TOAC as an ESR probe

V Monaco, F Formaggio, M Crisma… - Biopolymers …, 1999 - Wiley Online Library
Trichogin GA IV is a lipopeptaibol antibiotic characterized by the sequence nOct–Aib1–Gly–
Leu–Aib4–Gly–Gly–Leu–Aib8–Gly–Ile–Lol (nOct: n‐octanoyl; Aib: α‐aminoisobutyric acid; …

Conformational analysis of linear peptides: 5. Spectroscopic characterization of β-turns in Aib-containing oligopeptides in chloroform

GM Bonora, C Mapelli, C Toniolo, RR Wilkening… - International Journal of …, 1984 - Elsevier
Abstract 1 H nmr studies are reported for the α, α-dialkylated α-amino acid, α-
aminoisobutyric acid homopeptides Z-(Aib) n Ot-Bun= 3-5, in chloroform solution. The …

Conformational studies of poly (oxyethylene)-bound peptides and protein sequences

VNR Pillai, M Mutter - Accounts of Chemical Research, 1981 - ACS Publications
Conclusion Because far fewer gaseous species have identifiable UV spectra than have
characteristic far-infrared or in-frared spectra, the potential of these spectral regions for both …