This review highlights the recent advances, from 2015 to 2023, on the introduction of organo-
fluorine derivatives at the N-heteroarene core. Notable features considering new …

For nucleophilic monofluorination, amine/HF reagents such as Et3N⋅ 3HF, Pyr⋅ 9HF
(Olah's reagent) and similar combinations belong to the most frequently used fluoride …

A new phase transfer system for nucleophilic fluorination of alkyl halides with potassium
fluoride, based on the combination of 18-crown-6 and the bulky fluorinated alcohol 1, 1, 1, 3 …

We have developed a widely applicable (radio) fluoro-iodination of alkenes using readily
available and easily handled KF (18F). The reactions exhibited high functional group …

Alkali metal borohydrides present a rich source of energy dense materials of boron and
hydrogen, however their potential in propellants has been hitherto untapped. Potassium …

Nucleophilic fluorination of secondary aliphatic substrates, especially of halides, still
remains a challenge. Among the available reagents, TBAT belongs to one of the best …

Fluorination reactions are important in constructing organofluorine motifs, which contribute
to favorable biological properties in pharmaceuticals and agrochemicals. However …

TBAT (tetrabutylammonium difluorotriphenylsilicate) is an excellent homogeneous
nucleophilic fluorination reagent, but a high excess of the reagent was reported to be …

Nucleophilic fluorination of aromatic rings can be done via a cross-coupling reaction
catalyzed by palladium and biaryl monophosphine ligands such as AlPhos. Nevertheless …

The trifluoromethyl anion is a reactive species useful for the trifluoromethylation reaction of
organic compounds. However, this species is prone to an elimination process via the …