Progress in artificial metallonucleases

F Mancin, P Scrimin, P Tecilla - Chemical Communications, 2012 - pubs.rsc.org
The development of synthetic agents able to hydrolytically cleave DNA with high efficiency
and selectivity is still a fascinating challenge. Over the years, many examples have been …

Dinuclear copper (I) complexes of phenanthrolinyl-functionalized NHC ligands

B Liu, C Chen, Y Zhang, X Liu, W Chen - Organometallics, 2013 - ACS Publications
We have prepared a number of phenanthroline-functionalized imidazolium and triazolium
salts from 2-iodo-1, 10-phenanthroline and imidazole and triazole derivatives. Simple …

Di and tetranuclear Cu (II) complexes with simple 2-aminoethylpyridine: Magnetic properties, phosphodiester hydrolysis, DNA binding/cleavage, cytotoxicity and …

P Sureshbabu, QM Junaid, C Upadhyay, W Victoria… - Polyhedron, 2019 - Elsevier
Di and tetranuclear Cu (II) complexes,[Cu 2 (2-AEP) 4 (µ-Cl)](ClO 4) 3 (1) and [Cu 4 (µ 3-OH)
2 (µ 2-OH) 2 (2-AEP) 4 (µ 2-ClO 4) 2](ClO 4) 2 (2), with the simple 2-aminoethylpyridine (2 …

DNA damage and induction of apoptosis in pancreatic cancer cells by a new dinuclear bis (triazacyclonane) copper complex

D Montagner, V Gandin, C Marzano… - Journal of Inorganic …, 2015 - Elsevier
The dinuclear copper (II) complex [Cu 2 {bcmp (-H)}(μ-OH)](NO 3) 2· H 2 O (1, bcmp= 2, 6-
bis (1, 4, 7-triazacyclonon-1-ylmethyl)-4-methylphenol) has been synthesized and …

[HTML][HTML] Ultrasound-assisted fabrication of a new nano-rods 3D copper (II)-organic coordination supramolecular compound

Y Hanifehpour, V Safarifard, A Morsali… - Ultrasonics …, 2016 - Elsevier
High-energy ultrasound irradiation has been used for the synthesis of a new copper (II)
coordination supramolecular compound,[Cu 2 (μ-O 2 CCH 3) 2 (μ-OOCCH 3)(phen) 2](BF …

Mononuclear Cu (ii) and Zn (ii) complexes with a simple diamine ligand: synthesis, structure, phosphodiester binding and DNA cleavage studies

P Sureshbabu, AAJS Tjakraatmadja, C Hanmandlu… - Rsc Advances, 2015 - pubs.rsc.org
Two mononuclear complexes,[Cu (dach) 2 (ClO4) 2] 1a and [Zn (dach) 2](ClO4) 2 2a, with
simple 1, 2-diaminocyclohexane (dach) ligands were synthesized and characterized by …

Efficient Artificial Nucleases for Mediating DNA Cleavage Based on Tuning the Steric Effect in the Pyridyl Derivatives of Tripod Tetraamine‐Cobalt (II) Complexes

SD Kettenmann, FR Louka, E Marine… - European Journal of …, 2018 - Wiley Online Library
Four cobalt (II) complexes [Co (L1) Cl] PF6/ClO4 (C1‐PF6/C1‐ClO4),[Co (L2) Cl] PF6 (C2‐
PF6),[Co (L3) Cl] PF6/ClO4· H2O· CH3OH (C3‐PF6/C3‐ClO4· H2O· CH3OH) and [Co (L4) …

New discovery in crystallography: Correlation of terahertz time-domain spectra with crystal structures and photoluminescence properties of mononuclear/binuclear …

N Zhu, G Wang, S Lin, ZF Li, XL Xin, YP Yang, M Liu… - …, 2019 - pubs.rsc.org
In this paper, a series of mononuclear/binuclear Cu (I) complexes,[CuI (dpq)(PPh3)
2](CF3SO3)· CH3OH (1a),[CuI (dppz)(PPh3) 2](CF3SO3)· CH3OH (1b),[CuI2 (dpq) 2 (dppm) …

Targeting an artificial metal nuclease to DNA by a simple chemical modification and its drastic effect on catalysis

N Castilho, P Gabriel, TP Camargo… - ACS Medicinal …, 2019 - ACS Publications
A novel metal complex was synthesized containing a purine derived ligand in order to
increase its binding to DNA. We observed a huge increase in nuclease activity and, quite …

Structural and Magnetic Properties of Dimeric and Tetrameric Copper (II) Complexes with Simple Bidentate Ligands and Phosphate Bridges

P Sureshbabu, C Upadhyay, S Sabiah - ChemistrySelect, 2022 - Wiley Online Library
Abstract Monomeric [Cu (DACH)(L)] 2+(DACH= 1, 2‐diaminocyclohexane) heteroleptic
copper (II) complexes (1–4) on reaction with diphenyl phosphate yielded dinuclear …