Conspectus Noncovalent interactions (NCIs) have long interested a vast community of
chemists who investigated their “canonical categories” derived from descriptive …

The quest for sustainable ways to introduce diverse functional groups onto complex
scaffolds has made directed transition metal-catalysed C–H functionalization reactions a …

Herein, we describe the development of a Rh-catalyzed C–H acyloxylation under mild
electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was …

Investigations into C− H amidation reactions catalysed by cationic half‐sandwich d6 metal
complexes revealed that the indenyl‐derived catalyst [Ind* RhCl2] 2 significantly accelerated …

Transition metal catalysed direct sulfanylations of unreactive C–H bonds have become a
unique and straightforward synthetic strategy in late-stage C–S bond formation of relevant …

This review summarizes the more recent methods (since 2015) for the synthesis of
thioethers using homogeneous metals as catalysts. The thioether moiety can be found in …

C–H bond activation and functionalization using high-valent cobalt catalysis typically
involves a Co (III)/Co (I) catalytic cycle. Because of the lack of evidence and challenges …

Herein, an iridium (III)-catalysed electrooxidative intramolecular dehydrogenative C–H/N–H
coupling of unprotected 2-alkenyl anilines is described. The developed method allows the …

Transition-metal-catalyzed, directed intermolecular C–H bond functionalization is
synthetically useful but heavily underexplored in multiheteroatom heterocycle synthesis …

This study reports that the well-known Co (III) precursor Co (η5-Cp*) I2 (CO)(1) is an
effective precatalyst for dehydrocoupling reactions of phosphines. Reaction monitoring by …