Recent developments in catalytic amide bond formation

M Todorovic, DM Perrin - Peptide Science, 2020 - Wiley Online Library
Amide bond forming reactions are critical for both polypeptide synthesis and medicinal
chemistry. Most current approaches for amidation employ stoichiometric activating agents …

CoSe2 Subnanometer Belts with Se Vacancies and Ni Substitutions for the Efficient Electrosynthesis of High-Value-Added Nitriles Coupled with Hydrogen …

L Zeng, W Chen, Q Zhang, S Xu, W Zhang, F Lv… - ACS …, 2022 - ACS Publications
The electrosynthesis of organic amines to high-value-added nitriles coupled with hydrogen
generation is a highly efficient way to achieve carbon neutrality; however, the development …

Silicon compounds as stoichiometric coupling reagents for direct amidation

JJ Davies, DC Braddock, PD Lickiss - Organic & Biomolecular …, 2021 - pubs.rsc.org
Despite being one of the most frequently carried out chemical reactions in industry, there is
currently no amidation protocol that is regarded as safe, high yielding, environmentally …

En route to a heterogeneous catalytic direct peptide bond formation by Zr-based metal–organic framework catalysts

F de Azambuja, A Loosen, D Conic… - Acs …, 2021 - ACS Publications
Peptide bond formation is a challenging, environmentally and economically demanding
transformation. Catalysis is key to circumvent current bottlenecks. To date, many …

On the Use of Triarylsilanols as Catalysts for Direct Amidation of Carboxylic Acids

DC Braddock, BC Rowley, PD Lickiss… - The Journal of …, 2023 - ACS Publications
Triarylsilanols have been reported as the first silicon-centered molecular catalysts for direct
amidation of carboxylic acids with amines as identified after a screen of silanols, silanediols …

Tetramethyl orthosilicate (TMOS) as a reagent for direct amidation of carboxylic acids

DC Braddock, PD Lickiss, BC Rowley, D Pugh… - Organic …, 2018 - ACS Publications
Tetramethyl orthosilicate (TMOS) is shown to be an effective reagent for direct amidation of
aliphatic and aromatic carboxylic acids with amines and anilines. The amide products are …

Distinct Site Motifs Activate O2 and H2 on Supported Au Nanoparticles in Liquid Water

JS Adams, H Chen, T Ricciardulli… - ACS …, 2024 - ACS Publications
Au nanoparticles catalyze the activation and conversion of small molecules with rates and
kinetic barriers that depend on the dimensions of the nanoparticle, composition of the …

Synergistic effect of acidity and active phases for NiMo catalysts on dibenzothiophene hydrodesulfurization performance

Z Cao, X Zhang, R Guo, S Ding, P Zheng, J Fan… - Chemical Engineering …, 2020 - Elsevier
Abstract Serial Al-Ti-SBA-16 materials with highly ordered degree were successfully
synthesized by a simple two-step method. The characterization results showed that …

Immobilization of thiol-functionalized ionic liquids onto the surface of MIL-101 (Cr) frameworks by SCr coordination bond for biodiesel production

M Han, Y Li, Z Gu, H Shi, C Chen, Q Wang… - Colloids and Surfaces A …, 2018 - Elsevier
A novel functionalized MOF heterogeneous catalyst (MIL-101 (Cr)@ MBIAILs), 2-
Mercaptobenzimidazole ILs with electron-rich single bondSH groups immobilized onto the …

Iron-modified mesoporous silica as an efficient solid lewis acid catalyst for the Mukaiyama Aldol reaction

W Xu, T Ollevier, F Kleitz - ACS Catalysis, 2018 - ACS Publications
Fe-MCM-41 and Fe-SBA-15, two different iron-containing mesoporous silicas, were
successfully synthesized by a straightforward and versatile method using iron …