Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Principles and applications of photothermal catalysis

C Song, Z Wang, Z Yin, D Xiao, D Ma - Chem Catalysis, 2022 - cell.com
Solar energy provides an alternative, sustainable, and clean source of energy to meet the
global energy demands without extra carbon emissions. However, the utilization efficiency of …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H Xin, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G Xiang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …

Single-atom catalysts based on the metal–oxide interaction

R Lang, X Du, Y Huang, X Jiang, Q Zhang… - Chemical …, 2020 - ACS Publications
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …

Race on engineering noble metal single-atom electrocatalysts for water splitting

H Xu, Y Zhao, G He, H Chen - International Journal of Hydrogen Energy, 2022 - Elsevier
Constructing noble metal single-atom catalysts (NMSACs) is essential to boosting the water
splitting electrocatalysis by virtue of their maximum atom utilization and distinctive electronic …

Self‐accommodation induced electronic metal–support interaction on ruthenium site for alkaline hydrogen evolution reaction

C Li, SH Kim, HY Lim, Q Sun, Y Jiang… - Advanced …, 2023 - Wiley Online Library
Tuning the metal‐support interaction of supported metal catalysts has been found to be the
most effective approach to modulating electronic structure and improving catalytic …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

Review of carbon support coordination environments for single metal atom electrocatalysts (SACS)

W Song, C Xiao, J Ding, Z Huang, X Yang… - Advanced …, 2024 - Wiley Online Library
This topical review focuses on the distinct role of carbon support coordination environment
of single‐atom catalysts (SACs) for electrocatalysis. The article begins with an overview of …