In this review a historic overview is given of the biomimetic models synthesised since the
presence of nickel in hydrogenases was first reported in 1981. The crystal structure of the …

This review is focused on experimental work on dithiolene complexes and their usage as
photocatalysts for the cleavage of water. Several aspects of homogeneous and …

Ni-containing superoxide dismutase (NiSOD) is the most recently discovered member of the
class of metalloenzymes that detoxify the superoxide radical in aerobic organisms. In this …

A square-planar nickel (II) dithiolate complex is an active molecular catalyst for both
photoreduction of protons from water with a turnover number (> 1500) and electroreduction …

The synthesis and characterization of Pd (phen)(bdt)(1)(phen= 1, 10-phenanthroline, bdt= 1,
2-benzenedithiolate) is presented. 1 crystallizes in the monoclinic space group P 21/c, α …

The diamino-dithiolato N2S2 ligand N, N '-bis-2-methyl-mercaptopropyl-N, N '-
dimethylethylenediamine, H2 (bmmp-dmed), and its nickel (1) and zinc (2) complexes have …

In the absence of base, the reaction of [FeII (TMCS)] PF6 (1, TMCS= 1-(2-mercaptoethyl)-4,
8, 11-trimethyl-1, 4, 8, 11-tetraazacyclotetradecane) with peracid in methanol at− 20° C did …

The distal nickel site of acetyl-CoA synthase (Nid-ACS) and reduced nickel superoxide
dismutase (Ni-SOD) display similar square-planar NiIIN2S2 coordination environments. One …

Metal thiolate complexes can act as photosensitizers for the generation of singlet oxygen,
quenchers of singlet oxygen, and they may undergo chemical reactions with singlet oxygen …

The organometallic active sites in [NiFe]‐and [FeFe] H2ases are sensitive to oxygen in
varying degrees. The microorganisms that utilize these enzymes for their hydrogen …