The development of azide migration reactions is a formidable challenge because of the
potential competition of side processes driven by the release of molecular nitrogen. Here …

This report describes the stereoselective synthesis of 3-azido-tetralins,-chromanes, and-
tetrahydroquinolines via a tandem allylic azide rearrangement/Friedel–Crafts alkylation …

Azide compounds are widely used and especially, polymers bearing pendant azide groups
are highly desired in numerous fields. However, harsh reaction conditions are always …

The spontaneous rearrangement of allylic azides is thought to be a sigmatropic reaction.
Presented herein is a detailed investigation into the rearrangement of several allylic azides …

A highly regioselective Wacker oxidation has been developed for the oxidation of cinnamyl
azides. The catalytic oxidation tolerates the azide functionality, and more than 15 β-azido …

A domino [3, 3]-sigmatropic rearrangement sequence employing a sequential reversible
allylic azide rearrangement followed by an irreversible Overman reaction provides a new …

A base-controlled regiodivergent azidation of trifluoromethyl alkenyl triflates providing either
(E)-3-azido-1-aryl-4, 4, 4-trifluorobut-1-ene (CF3-containing allyl azides) or (Z)-1-azido-1 …

Allylic azides are underutilized in organic synthesis when compared to other organic azides
or other allylic functionality. This is likely because allylic azides rearrange at room …

In this study, dedicated to Prof. Dr. Yaşar Sütbeyaz (1950–2016), intramolecular interactions
in (1S (R), 2S (R))-2-azidocycloalk-3-en-1-ols and (1S (R), 2S (R))-2-azidocycloalk-3-en-1-yl …

Peptide-based therapeutics are currently in great demand but often suffer from rapid
clearance and accumulation in off-target tissues which continue to present barriers in their …