Multiscale and multistep ordering of flow-induced nucleation of polymers
Flow-induced crystallization (FIC) is a typical nonequilibrium phase transition and a core
industry subject for the largest group of commercially useful polymeric materials …
industry subject for the largest group of commercially useful polymeric materials …
Shear-induced transitions in colloidal and polymeric liquids
AY Malkin - Advances in Colloid and Interface Science, 2021 - Elsevier
This review reflects different aspects of wide current studies of the phenomena related to the
shear-induced structure transformation in various complex liquids. Experimental data, being …
shear-induced structure transformation in various complex liquids. Experimental data, being …
Competitive growth of α-and β-crystals in β-nucleated isotactic polypropylene under shear flow
YH Chen, YM Mao, ZM Li, BS Hsiao - Macromolecules, 2010 - ACS Publications
It has been well established that, although both shear flow and β-nucleating agent could
separately induce β-crystals in isotactic polypropylene (iPP) in an efficient manner, their …
separately induce β-crystals in isotactic polypropylene (iPP) in an efficient manner, their …
An assessment of models for flow-enhanced nucleation in an n-alkane melt by molecular simulation
DA Nicholson, GC Rutledge - Journal of Rheology, 2019 - pubs.aip.org
Flow-enhanced nucleation of the crystal phase under shear and uniaxial extension for a
monodisperse melt of n-pentacontahectane (C 150 H 302 or C150) chains was studied by …
monodisperse melt of n-pentacontahectane (C 150 H 302 or C150) chains was studied by …
Flow-induced crystallization of isotactic polypropylene: Modeling formation of multiple crystal phases and morphologies
PC Roozemond, TB van Erp, GWM Peters - Polymer, 2016 - Elsevier
A modeling framework is presented to describe flow-induced crystallization of isotactic
polypropylene at elevated pressures in multiple crystal phases and morphologies. By …
polypropylene at elevated pressures in multiple crystal phases and morphologies. By …
A stretch-based model for flow-enhanced nucleation of polymer melts
RJA Steenbakkers, GWM Peters - Journal of Rheology, 2011 - pubs.aip.org
(2001)] to flow-enhanced pointlike nucleation, which can lead to number densities of
spherulites multiplied by orders of magnitude. Excellent agreement between simulations …
spherulites multiplied by orders of magnitude. Excellent agreement between simulations …
Effect of particles on the flow-induced crystallization of polypropylene at processing speeds
M D'Haese, P Van Puyvelde, F Langouche - Macromolecules, 2010 - ACS Publications
The effect of particles with different diameters on flow-induced crystallization from low shear
rates to processing speeds is studied using mixtures of polypropylene and zinc oxide with …
rates to processing speeds is studied using mixtures of polypropylene and zinc oxide with …
Self-organization in the flow of complex fluids (colloid and polymer systems): Part 1: Experimental evidence
AY Malkin, AV Semakov, VG Kulichikhin - Advances in Colloid and …, 2010 - Elsevier
Different types of regular and irregular self-organized structures observed in deformation of
colloid and polymer substances (“complex fluids”) are discussed and classified. This review …
colloid and polymer substances (“complex fluids”) are discussed and classified. This review …
Flow‐induced crystallization
GWM Peters, L Balzano… - Handbook of polymer …, 2013 - Wiley Online Library
Molecular properties are reflected in the rheological and crystallization behavior. The first
task is to design and use some well‐defined experiments that reveal all these features …
task is to design and use some well‐defined experiments that reveal all these features …
A fundamental rule: Determining the importance of flow prior to polymer crystallization
C McIlroy - Physics of Fluids, 2019 - pubs.aip.org
A continuum-level model for nonisothermal polymer crystallization following a complex flow
is presented, along with a fundamental rule that may be employed to determine if the flow …
is presented, along with a fundamental rule that may be employed to determine if the flow …