Defect Engineering of MOF‐Based Membrane for Gas Separation

S Li, W Han, QF An, KT Yong… - Advanced Functional …, 2023 - Wiley Online Library
Metal–organic frameworks (MOFs) are highly versatile materials that have been identified as
promising candidates for membrane‐based gas separation applications due to their …

The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks

Z Hu, Y Wang, D Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …

Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis

GC Shearer, S Chavan, S Bordiga, S Svelle… - Chemistry of …, 2016 - ACS Publications
Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when
synthesized in the presence of monocarboxylic acid modulators under the most commonly …

MOFs as proton conductors–challenges and opportunities

P Ramaswamy, NE Wong, GKH Shimizu - Chemical Society Reviews, 2014 - pubs.rsc.org
Proton conducting materials have garnered immense attention for their role as electrolytes in
fuel cells. Metal Organic Frameworks (MOFs) and coordination polymers have recently been …

Catalytic zirconium/hafnium-based metal–organic frameworks

M Rimoldi, AJ Howarth, MR DeStefano, L Lin… - Acs …, 2017 - ACS Publications
Metal–organic frameworks (MOFs) are highly versatile materials that find applications in
several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and …

Structural defects in metal–organic frameworks (MOFs): Formation, detection and control towards practices of interests

J Ren, M Ledwaba, NM Musyoka, HW Langmi… - Coordination Chemistry …, 2017 - Elsevier
Research on metal–organic framework (MOF) materials has gathered increasing interest
starting from the early excitement as porous materials for gas storage down to various novel …

Evaluation of Brønsted acidity and proton topology in Zr-and Hf-based metal–organic frameworks using potentiometric acid–base titration

RC Klet, Y Liu, TC Wang, JT Hupp… - Journal of Materials …, 2016 - pubs.rsc.org
Potentiometric acid–base titration is introduced as a method to evaluate pKa values
(Brønsted acidity) of protons present in the nodes of water stable Zr6-and Hf6-based metal …

Bifunctional Imidazolium-Based Ionic Liquid Decorated UiO-67 Type MOF for Selective CO2 Adsorption and Catalytic Property for CO2 Cycloaddition with Epoxides

LG Ding, BJ Yao, WL Jiang, JT Li, QJ Fu, YA Li… - Inorganic …, 2017 - ACS Publications
A bifunctional robust and highly porous imidazolium-based ionic liquid decorated UiO-67
type MOF (UiO-67-IL, 1) was successfully constructed via solvothermal assembly of the …

Microwave-assisted synthesis of zirconium-based metal organic frameworks (MOFs): Optimization and gas adsorption

R Vakili, S Xu, N Al-Janabi, P Gorgojo… - Microporous and …, 2018 - Elsevier
Microwave-assisted synthesis of zirconium (Zr) based metal organic frameworks (MOFs)
were performed and the yield and porous property of UiO-67 was optimized by varying the …

Metal–organic framework (MOF) defects under control: insights into the missing linker sites and their implication in the reactivity of zirconium-based frameworks

OV Gutov, MG Hevia, EC Escudero-Adan… - Inorganic …, 2015 - ACS Publications
For three-dimensional (3D) metal–organic frameworks (MOFs), the presence and nature of
structural defects has been recognized as a key factor shaping the material's physical and …