NHCs in main group chemistry
V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …
1990s, these divalent carbon species have become a common and available class of …
N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …
research fields, and it is not possible to imagine modern transition metal and main group …
N-Heterocyclic Carbene Main-Group Chemistry: A Rapidly Evolving Field
Y Wang, GH Robinson - Inorganic Chemistry, 2014 - ACS Publications
This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic
carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of …
carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of …
Sodium phosphaethynolate, Na (OCP), as a “P” transfer reagent for the synthesis of N-heterocyclic carbene supported P 3 and PAsP radicals
AM Tondreau, Z Benkő, JR Harmer… - Chemical Science, 2014 - pubs.rsc.org
Sodium phosphaethynolate, Na (OCP), reacts as a P− transfer reagent with the imidazolium
salt [DippNHC–H][Cl][DippNHC= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene] to give …
salt [DippNHC–H][Cl][DippNHC= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene] to give …
Phosphine-stabilized germylidenylpnictinidenes as synthetic equivalents of heavier nitrile and isocyanide in cycloaddition reactions with alkynes
The reactions of chlorogermylene MsFluind t Bu-GeCl 1, supported by a sterically
encumbered hydrindacene ligand MsFluind t Bu, with NaPCO (dioxane) 2.5 and NaAsCO …
encumbered hydrindacene ligand MsFluind t Bu, with NaPCO (dioxane) 2.5 and NaAsCO …
Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds
L Dostál - Coordination Chemistry Reviews, 2017 - Elsevier
The chemistry of low-valent main group compounds represents one of the most exciting and
quickly developing areas in the field of organometallic and organoelement chemistry. In this …
quickly developing areas in the field of organometallic and organoelement chemistry. In this …
Triamidoamine–Uranium (IV)‐Stabilized Terminal Parent Phosphide and Phosphinidene Complexes
BM Gardner, G Balázs, M Scheer, F Tuna… - Angewandte …, 2014 - Wiley Online Library
Abstract Reaction of [U (TrenTIPS)(THF)][BPh4](1; TrenTIPS= N {CH2CH2NSi (iPr) 3} 3) with
NaPH2 afforded the novel f‐block terminal parent phosphide complex [U …
NaPH2 afforded the novel f‐block terminal parent phosphide complex [U …
N‐Heterocyclic Carbene–Phosphinidyne Transition Metal Complexes
A Doddi, D Bockfeld, T Bannenberg… - Angewandte Chemie …, 2014 - Wiley Online Library
The N‐heterocyclic carbene–phosphinidene adduct IPr PSiMe3 is introduced as a synthon
for the preparation of terminal carbene–phosphinidyne transition metal complexes of the …
for the preparation of terminal carbene–phosphinidyne transition metal complexes of the …
Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?
Z Benedek, T Szilvási - RSC Advances, 2015 - pubs.rsc.org
We investigated the potential application of experimentally characterized low-valent silicon
compounds as transition metal ligands by computing the most important ligand properties, σ …
compounds as transition metal ligands by computing the most important ligand properties, σ …
From a phosphaketenyl‐functionalized germylene to 1, 3‐digerma‐2, 4‐diphosphacyclobutadiene
The first 4π‐electron resonance‐stabilized 1, 3‐digerma‐2, 4‐diphosphacyclobutadiene
[LH2Ge2P2] 4 (LH= CH [CHNDipp] 2 Dipp= 2, 6‐iPr2C6H3) with four‐coordinate …
[LH2Ge2P2] 4 (LH= CH [CHNDipp] 2 Dipp= 2, 6‐iPr2C6H3) with four‐coordinate …