Chiral organosulfur compounds are not only widely distributed in bioactive natural products
and pharmaceuticals, but also play a significant role in chiral ligands/catalysts. Throughout …

The construction of N–N axially chiral motifs is an important research topic, owing to their
wide occurrence in natural products, pharmaceuticals and chiral ligands. One efficient …

N‐Heterocyclic carbene (NHC) organocatalysis has emerged as a powerful tool in the field
of modern organic synthesis especially in the asymmetric construction of various cyclic …

Axially chiral diaryl ethers are present in numerous natural products and bioactive
molecules. However, only few catalytic enantioselective approaches have been established …

We present herein an unprecedented stereoselective synthesis of triaryl-2-pyrones with
monoaxial or contiguous diaxes from readily available starting materials. This N-heterocyclic …

Atropisomers bearing multiple stereogenic axes are of increasing importance to the field of
material science, pharmaceuticals, and catalysis. However, the atroposelective construction …

Although the atroposelective synthesis of biaryls and related compounds bearing axially
chiral C–C bonds is well-known, the synthesis of axially chiral C–N bond-containing …

Herein, we describe our design and synthesis of novel chiral monophosphine ligands by the
short-step addition of chiral lactates as side chains to the well-known ligand SPhos/RuPhos …

A chiral carbene-catalyzed chemo-and enantioselective reaction with racemic biaryl
aldehydes and α-bromoenals is developed for access to axially chiral 2-arylbenzaldehydes …

Abstract A variety of 5‐indo‐1‐yl pyran‐2‐ones with an N− C axis were prepared via a
carbene‐catalyzed oxidative [3+ 3] annulation of indole‐1‐pyruvate esters and enals …