[HTML][HTML] Advances in the synthesis of acyclic peroxides

H Gandhi, K O'Reilly, MK Gupta, C Horgan… - RSC …, 2017 - pubs.rsc.org
Peroxide-containing compounds are an attractive synthetic target, given their widespread
abundance in nature, with many displaying potent antimalarial and antimicrobial properties …

Stereoelectronic effects in the formation of 5-and 6-membered rings: the role of Baldwin's rules

CD Johnson - Accounts of chemical research, 1993 - ACS Publications
The demonstration by Dunitz and hisco-workers1 of favored trajectories for the approach of
one reactant molecule toward another led to the formulation of rules governing the ease of …

Triflic Acid‐Functionalized Silica‐Coated Magnetic Nanoparticles as a Magnetically Separable Catalyst for Synthesis of gem‐Dihydroperoxides

YH Liu, J Deng, JW Gao… - Advanced Synthesis & …, 2012 - Wiley Online Library
Triflic acid‐functionalized silica‐coated magnetic nanoparticles [γ‐Fe2O3@ SiO2‐TfOH]
were readily prepared and identified as an effictive catalyst for the transformation of …

Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular α-Effect

E Juaristi, G dos Passos Gomes… - Journal of the …, 2017 - ACS Publications
The first systematic study of the intramolecular α-effect, both in the stable ground-state
structures and in the high-energy intermediates, was accomplished using the anomeric …

Catalyst development for the synthesis of ozonides and tetraoxanes under heterogeneous conditions: Disclosure of an unprecedented class of fungicides for …

IA Yaremenko, PS Radulov… - … A European Journal, 2020 - Wiley Online Library
Abstract The catalyst H3+ xPMo12− x+ 6Mox+ 5O40 supported on SiO2 was developed for
peroxidation of 1, 3‐and 1, 5‐diketones with hydrogen peroxide with the formation of …

Ozone-free synthesis of ozonides: assembling bicyclic structures from 1, 5-diketones and hydrogen peroxide

IA Yaremenko, GP Gomes, PS Radulov… - The Journal of …, 2018 - ACS Publications
Reactions of 1, 5-diketones with H2O2 open an ozone-free approach to ozonides. Bridged
ozonides are formed readily at room temperature in the presence of strong Brønsted or …

Cyclic peroxides as promising anticancer agents: In vitro cytotoxicity study of synthetic ozonides and tetraoxanes on human prostate cancer cell lines

IA Yaremenko, MA Syroeshkin, DO Levitsky… - Medicinal Chemistry …, 2017 - Springer
Synthetic ozonides and tetraoxanes were shown to have high cytotoxicity in vitro when
tested on androgen-independent prostate cancer cell lines DU145 and PC3, which is in …

Stereoelectronic control in the ozone‐free synthesis of ozonides

G dos Passos Gomes, IA Yaremenko… - Angewandte …, 2017 - Wiley Online Library
The value of stereoelectronic guidelines is illustrated by the discovery of a convenient,
ozone‐free synthesis of bridged secondary ozonides from 1, 5‐dicarbonyl compounds and …

A Broadly Applicable Mild Method for the Synthesis of gem-Diperoxides from Corresponding Ketones or 1,3-Dioxolanes

Y Li, HD Hao, Q Zhang, Y Wu - Organic Letters, 2009 - ACS Publications
A Broadly Applicable Mild Method for the Synthesis of gem-Diperoxides from Corresponding
Ketones or 1,3-Dioxolanes | Organic Letters ACS ACS Publications C&EN CAS Find my …

Synthesis of acyclic geminal bis-peroxides

OV Bityukov, VA Vil', AO Terent'ev - Russian Journal of Organic Chemistry, 2021 - Springer
The review covers the state of the art in methods of synthesis of acyclic geminal bis-
peroxides, including bis-hydroperoxides, bis (1-hydroperoxyalkyl) peroxides, and 1 …