Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes | Chemical Reviews ACS
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Catalytic, stereoselective N-heterocyclic carbene-catalyzed reactions facilitate efficient
construction of many different heterocyclic compounds, such as the enantioenriched 5 …

The use of NHCs for generating homoenolate species has gained widespread popularity in
recent years. A number of highly stereoselective processes of NHC-homoenolates have …

The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …

Phosphorus‐substituted heterocycles represent an important class of organophosphorus
compounds, which not only widely exist in biologically active pharmaceuticals …

A catalytic method for the enantioselective and C4-selective functionalization of pyridine
derivatives is yet to be developed. Herein, we report an efficient method for the asymmetric β …

A highly enantioselective N‐heterocyclic carbene (NHC) catalyzed formal [3+ 2] annulation
of α, β‐unsaturated aldehydes with azaaurones or aurone generating spiro‐heterocycles …

A regio-and enantioselective formal [4+ 3] annulation reaction between enals and in situ
formed azoalkenes has been achieved. A diverse set of 1, 2-diazepine derivatives were …

A sterically hindered homoenolate has been generated by the NHC‐catalyzed conjugate
umpolung of β, β‐disubstituted enals and successfully employed in a facile stereoselective …

Disclosed here is NHC-catalyzed direct intermolecular trapping of the ketone oxygen atom
with the acyl azolium intermediate. The overall reaction is a dynamic kinetic resolution …