Trends in the Diels–Alder reaction in polymer chemistry
The Diels–Alder (DA) reaction is regarded as quite a useful strategy in organic and
macromolecular syntheses. The reversibility of this reaction and the advent of self-repair …
macromolecular syntheses. The reversibility of this reaction and the advent of self-repair …
Click chemistry strategies for the accelerated synthesis of functional macromolecules
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …
materials with precise control over architecture and functionality. In this review, we provide a …
Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …
Click chemistry with cyclopentadiene
BJ Levandowski, RT Raines - Chemical reviews, 2021 - ACS Publications
Cyclopentadiene is one of the most reactive dienes in normal electron-demand Diels–Alder
reactions. The high reactivities and yields of cyclopentadiene cycloadditions make them …
reactions. The high reactivities and yields of cyclopentadiene cycloadditions make them …
Click to Self‐immolation: A “Click” Functionalization Strategy towards Triggerable Self‐Immolative Homopolymers and Block Copolymers
Self‐immolative polymers (SIPs) are a class of degradable macromolecules that undergo
stimuli‐triggered head‐to‐tail depolymerization. However, a general approach to readily …
stimuli‐triggered head‐to‐tail depolymerization. However, a general approach to readily …
Enantioselective Total Synthesis of (+)-Pedrolide
M Fadel, EM Carreira - Journal of the American Chemical Society, 2023 - ACS Publications
The first total synthesis of (+)-pedrolide, a tigliane-derived diterpenoid featuring an
unprecedented 5–5–6–6–3 carbon skeleton, is reported. Key to the approach is the …
unprecedented 5–5–6–6–3 carbon skeleton, is reported. Key to the approach is the …
Tunable photothermal actuation enabled by photoswitching of donor–acceptor Stenhouse adducts
We report a visible light-responsive bilayer actuator driven by the photothermal properties of
a unique molecular photoswitch: donor–acceptor Stenhouse adduct (DASA). We …
a unique molecular photoswitch: donor–acceptor Stenhouse adduct (DASA). We …
Harnessing Activated Alkyne-Hydroxyl “Click” Chemistry for Degradable and Self-Healing Poly (urea vinyl ether ester) s
A Maity, J Chen, N Wilson-Faubert, A Laventure… - …, 2023 - ACS Publications
The growing impact of polymers in modern-day applications necessitates the development
of novel polymeric materials with versatile properties derived from readily available …
of novel polymeric materials with versatile properties derived from readily available …
Tailoring the Architecture of Molecular Bottlebrushes via Click Grafting‐Onto Strategy
Y Shi, W Hou, Z Li, Y Chen - Macromolecular Rapid …, 2023 - Wiley Online Library
Molecular bottlebrush (MBB) refer to a synthetic macromolecule, in which a mass of
polymeric side chains (SCs) are covalently connected to a macromolecular backbone …
polymeric side chains (SCs) are covalently connected to a macromolecular backbone …
Efficient Metal-Free Norbornadiene–Maleimide Click Reaction for the Formation of Molecular Bottlebrushes
A highly efficient metal-free grafting-onto strategy based on the cyclopentadiene (Cp)–
maleimide click reaction was developed for the preparation of molecular bottlebrushes …
maleimide click reaction was developed for the preparation of molecular bottlebrushes …