Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

Because of their interesting structures and bonding and potentials as motifs for new
nanomaterials, size-selected boron clusters have received tremendous interest in recent …

Understanding and exploiting the redox properties of uranium is of great importance
because uranium has a wide range of possible oxidation states and holds great potential for …

Two-electron oxidations are ubiquitous and play a key role in the synthesis and catalysis.
For transition metals and actinides, two-electron oxidation often takes place at a single-metal …

This review comprehensively covers the coordination chemistry of elemental phosphorus
during the years 2011–2020. The main part is dedicated to the activation of white …

A fundamental aspect of any element is the range of oxidation states accessible for useful
chemistry. This tutorial describes the recent expansion of the number of oxidation states …

Flash reduction of Cp′ 3U (Cp′= C5H4SiMe3) in a column of potassium graphite in the
presence of 2.2. 2-cryptand generates crystalline [K (2.2. 2-cryptand)][Cp′ 3U], the first …

We present a family of trigonal pyramidal iron (II) complexes supported by tris (pyrrolyl-α-
methyl) amine ligands of the general formula [M (solv) n][(tpaR) Fe](M= Na, R= tert-butyl (1) …

Two-electron reduction of the amidate-supported U (III) mono (arene) complex U (TDA) 3 (2)
with KC8 yields the anionic bis (arene) complex [K [2.2. 2] cryptand][U (TDA) 2](3)(TDA= N …

Metal NHC complexes have been known for over 50 years, but only during the last 15 have
they been studied as potential catalysts. N-heterocyclic carbene (NHC) complexes are often …