Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Efficient and sustainable methods for carbon dioxide capture are highly sought after. Mature
technologies involve chemical reactions that absorb CO2, but they have many drawbacks …

In this Minireview we outline the development of cyclic aliphatic moieties as ligands in metal‐
organic frameworks (MOFs), with a focus on the relationship between ligand design and …

One of the most critical environmental issues of our age is the escalating release of CO2 into
the atmosphere. Separation technologies with low energy footprints may be an effective way …

Herein, by using pillaring ligands with different lengths, two copper-based metal–organic
frameworks, compounds 1 (Cu2 (bada) 2 (dabco)) and 2 (Cu2 (bada) 2 (bipy))(bada= 4, 4 …

Porous organic polymers (POPs), known for their high surface area and porosity, were
prepared starting from tetraphenyl tetrahedral-shaped building blocks and corrole …

The dinuclear mesocate [Fe2L3](BF4) 4, 1, is a supramolecular building block for a
microporous material. Structural analysis reveals that extensive noncovalent interactions in …

The properties of adamantane render it an attractive building block towards the synthesis of
robust frameworks. This work describes the synthesis of the L-shaped 1, 3-bis (3 …

Porous polymer show great potential for CO2 capture owing to its high specific surface area,
adjustable porous structure and chemical structure. Herein, a novel CO2 adsorption …

A series of solvatomorphic structures of tetrakis (4-dihydroxyborylphenyl) adamantane, 1,
have been prepared and analyzed by single crystal X-ray diffraction methods …