Recent progress in synthetic applications of hypervalent iodine (III) reagents
A Yoshimura, VV Zhdankin - Chemical Reviews, 2024 - ACS Publications
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …
Chemodivergent reactions
IP Beletskaya, C Nájera, M Yus - Chemical Society Reviews, 2020 - pubs.rsc.org
An important strategy for the efficient generation of diversity in molecular structures is the
utilization of common starting materials in chemodivergent transformations. The most …
utilization of common starting materials in chemodivergent transformations. The most …
Fused benzo [1, 3] thiazine-1, 2, 3-triazole hybrids: Microwave-assisted one-pot synthesis, in vitro antibacterial, antibiofilm, and in silico ADME studies
ER Sucharitha, TM Krishna, R Manchal… - Bioorganic & Medicinal …, 2021 - Elsevier
In this paper, we report an efficient one-pot three-component reaction sequences comprising
Cu (I)-catalyzed 1, 3-dipolar cycloaddition (CuAAC) followed by Cu-catalyzed arylation of …
Cu (I)-catalyzed 1, 3-dipolar cycloaddition (CuAAC) followed by Cu-catalyzed arylation of …
Photo-induced stereo-and regiospecific sulfonylation of C–C multiple bonds exploiting the dual reactivity of sulfonium iodate (i) species
Vinyl sulfones are privileged motifs for assembling prevalent biologically active molecules
and represent “gateway functional groups” in medicinal chemistry and drug discovery …
and represent “gateway functional groups” in medicinal chemistry and drug discovery …
On-DNA alkyne iodination and acetylenic coupling as a useful tool for DEL synthesis
A Luo, H Zhou, Q Zhou, Q Hua, X Zhao, X Yu… - Bioconjugate …, 2022 - ACS Publications
1-Iodoalkynes and 1, 3-diynes are versatile chemical intermediates and pharmaceutically
valuable ingredients. In this study, copper mediated on-DNA alkyne iodination and Cadiot …
valuable ingredients. In this study, copper mediated on-DNA alkyne iodination and Cadiot …
Regio-and stereoselective synthesis of 1, 2-dihaloalkenes using in-situ-generated ICl, IBr, BrCl, I2, and Br2
X Zeng, S Liu, Y Yang, Y Yang, GB Hammond, B Xu - Chem, 2020 - cell.com
We describe a catalyst-free 1, 2-trans-dihalogenation of alkynes with an unprecedented
substrate scope and exclusive regio-and stereoselectivity. This versatile dihalogenation …
substrate scope and exclusive regio-and stereoselectivity. This versatile dihalogenation …
Syntheses of 3 H-1, 2, 4-triazol-3-ones by copper-promoted oxidative N–N bond formation of amidines with isocyanates
B Liang, X Cai, JY Liu, J Huang, Y Chen… - Organic Chemistry …, 2024 - pubs.rsc.org
This study presents an efficient strategy for constructing 3H-1, 2, 4-triazol-3-ones via a
copper-promoted [3+ 2] annulation reaction of amidine hydrochlorides and isocyanates. This …
copper-promoted [3+ 2] annulation reaction of amidine hydrochlorides and isocyanates. This …
Regiospecific Synthesis of 1, 4-Diaryl-5-cyano-1, 2, 3-triazoles and Their Photoconversion to 2-or 3-Cyanoindoles
We report the synthesis of 1, 4-diaryl-5-cyano-1, 2, 3-triazoles from azides and alkynes via
two copper-mediated steps. Aryl-substituted cyanotriazoles are emissive in nonpolar …
two copper-mediated steps. Aryl-substituted cyanotriazoles are emissive in nonpolar …
Visible-light activated metal catalyst-free vicinal diazidation of olefins with sulfonium iodate (I) species
A visible light-induced vicinal diazidation of various alkenes using stable sulfonium bis
(acetoxy) iodate (I) and sodium azide as a radical precursor is described. The …
(acetoxy) iodate (I) and sodium azide as a radical precursor is described. The …
Catalytic asymmetric chemodivergent C2 alkylation and [3+ 2]-cycloaddition of 3-methylindoles with aziridines
Y Xu, F Chang, W Cao, X Liu, X Feng - ACS Catalysis, 2018 - ACS Publications
Highly enantioselective C2 alkylation and inverse-electron-demand [3+ 2]-cycloaddition of 3-
methylindoles with 2, 2′-diester aziridine were accomplished. The chemodivergent …
methylindoles with 2, 2′-diester aziridine were accomplished. The chemodivergent …