Recent advances in catalytic [3, 3]-sigmatropic rearrangements
Carbon–carbon bond formation by [3, 3]-sigmatropic rearrangement is a fundamental and
powerful method that has been used to build organic molecules for a long time. Initially …
powerful method that has been used to build organic molecules for a long time. Initially …
Diastereo‐and Enantioselective Construction of Stereochemical Arrays Exploiting Non‐Classical Hydrogen Bonding in Enolborates
M Li, S Scheeff, J Chen, RC Johnston… - … A European Journal, 2024 - Wiley Online Library
We report a copper‐catalyzed reductive aldol addition to aldehydes and ketones, with
pinacolborane as stoichiometric reductant, that results in the generation of stereodefined syn …
pinacolborane as stoichiometric reductant, that results in the generation of stereodefined syn …