Catalytic hydrothiolation: counterion-controlled regioselectivity

XH Yang, RT Davison, SZ Nie, FA Cruz… - Journal of the …, 2019 - ACS Publications
In this Article, we expand upon the catalytic hydrothiolation of 1, 3-dienes to afford either
allylic or homoallylic sulfides with high regiocontrol. Mechanistic studies support a pathway …

Contact allergens formed on air exposure of linalool. Identification and quantification of primary and secondary oxidation products and the effect on skin sensitization

M Sköld, A Börje, E Harambasic… - Chemical research in …, 2004 - ACS Publications
Linalool (3, 7-dimethyl-1, 6-octadien-3-ol) is an important fragrance chemical, frequently
used in scented products because of its fresh, flowery odor. Linalool is an unsaturated …

Transition-metal-free synthesis of vinyl sulfones via tandem cross-decarboxylative/coupling reactions of sodium sulfinates and cinnamic acids

Y Xu, X Tang, W Hu, W Wu, H Jiang - Green Chemistry, 2014 - pubs.rsc.org
A transition-metal-free synthesis of vinyl sulfones, utilizing sodium sulfinates and cinnamic
acids through tandem cross-decarboxylative/coupling reactions, has been developed. This …

Synthesis, spectral characterization, crystal structure and catalytic activity of a novel dioxomolybdenum Schiff base complex containing 4-aminobenzhydrazone ligand …

H Kargar, M Nateghi-Jahromi… - Journal of Molecular …, 2022 - Elsevier
A novel dioxomolybdenum Schiff base complex,[MoO 2 (L)(H 2 O)], was synthesized by the
reaction of MoO 2 (acac) 2 and an ONO donor Schiff base ligand (H 2 L:(E)-4-amino-N'-(3 …

Chromium (VI) oxide catalyzed oxidation of sulfides to sulfones with periodic acid

L Xu, J Cheng, ML Trudell - The Journal of organic chemistry, 2003 - ACS Publications
A highly efficient and selective oxidation of sulfides to sulfones with periodic acid catalyzed
by CrO3 is described. A variety of electron-rich and electron-deficient sulfides were oxidized …

Tetra-(tetraalkylammonium) octamolybdate catalysts for selective oxidation of sulfides to sulfoxides with hydrogen peroxide

C Yang, Q Jin, H Zhang, J Liao, J Zhu, B Yu, J Deng - Green Chemistry, 2009 - pubs.rsc.org
Tetra-(tetraalkylammonium) octamolybdate catalysts are successfully applied in the
selective oxidation of various sulfides to sulfoxides with 30% aqueous hydrogen peroxide as …

Selective oxidation of sulfides to sulfoxides and sulfones at room temperature using H2O2 and a Mo (VI) salt as catalyst

K Jeyakumar, DK Chand - Tetrahedron Letters, 2006 - Elsevier
Selective oxidation of sulfides to sulfoxides and sulfones is achieved by H2O2 using
MoO2Cl2 as the catalyst. Various substituted sulfides having functional groups such as …

Direct Allylic C(sp3)–H Thiolation with Disulfides via Visible Light Photoredox Catalysis

J Kim, B Kang, SH Hong - ACS Catalysis, 2020 - ACS Publications
In spite of the wide utility of allyl thioethers, the direct catalytic allylic C (sp3)–H thiolation
remains elusive. Herein, we report the direct allylic C (sp3)–H thiolation mediated by visible …

Highly atom-economic, catalyst-and solvent-free oxidation of sulfides into sulfones using 30% aqueous H 2 O 2

M Jereb - Green chemistry, 2012 - pubs.rsc.org
Highly atom-efficient oxidation of sulfides into sulfones under solvent-and catalyst-free
reaction conditions using a 30% aqueous solution of H2O2 at 75° C is reported. A …

A copper (II)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes

R Mao, Z Yuan, R Zhang, Y Ding, X Fan… - Organic Chemistry …, 2016 - pubs.rsc.org
A three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes
catalyzed by copper (II) bromide is developed, which provides an efficient route to (E) …