The emerging applications of sulfur (VI) fluorides in catalysis

C Lee, AJ Cook, JE Elisabeth, NC Friede… - ACS …, 2021 - ACS Publications
The past decade has witnessed remarkable growth of catalytic transformations in organic
sulfur (VI) fluoride chemistry. This Perspective concentrates exclusively on foundational …

Radical Hydro‐Fluorosulfonylation of Unactivated Alkenes and Alkynes

P Wang, H Zhang, M Zhao, S Ji, L Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …

Photoredox catalytic radical fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical precursor

P Wang, H Zhang, X Nie, T Xu, S Liao - Nature Communications, 2022 - nature.com
Sulfonyl fluorides have attracted considerable and growing research interests from various
disciplines, which raises a high demand for novel and effective methods to access this class …

Electrochemical Oxo‐Fluorosulfonylation of Alkynes under Air: Facile Access to β‐Keto Sulfonyl Fluorides

D Chen, X Nie, Q Feng, Y Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Radical fluorosulfonylation is emerging as an appealing approach for the synthesis of
sulfonyl fluorides, which have widespread applications in many fields, in particular in the …

SuFEx-enabled, agnostic discovery of covalent inhibitors of human neutrophil elastase

Q Zheng, JL Woehl, S Kitamura… - Proceedings of the …, 2019 - National Acad Sciences
Sulfur fluoride exchange (SuFEx) has emerged as the new generation of click chemistry. We
report here a SuFEx-enabled, agnostic approach for the discovery and optimization of …

Introducing A New Class of Sulfonyl Fluoride Hubs via Radical Chloro‐Fluorosulfonylation of Alkynes

X Nie, T Xu, Y Hong, H Zhang, C Mao… - Angewandte Chemie …, 2021 - Wiley Online Library
Sulfonyl fluorides have widespread applications in many important fields, including ligation
chemistry, chemical biology, and drug discovery. Therefore, new methods to increase the …

Radical fluorosulfonylation: accessing alkenyl sulfonyl fluorides from alkenes

X Nie, T Xu, J Song, A Devaraj, B Zhang… - Angewandte …, 2021 - Wiley Online Library
Sulfonyl fluorides have widespread applications in many fields. In particular, their unique
biological activity has drawn considerable research interest in the context of chemical …

Arenesulfonyl fluoride synthesis via copper-catalyzed fluorosulfonylation of arenediazonium salts

Y Liu, D Yu, Y Guo, JC Xiao, QY Chen, C Liu - Organic letters, 2020 - ACS Publications
We report herein a general and practical copper-catalyzed fluorosulfonylation reaction of a
wide range of abundant arenediazonium salts to smoothly prepare various arenesulfonyl …

Recent Advances in Developing Radical Methods for the Synthesis of Aliphatic Sulfonyl Fluorides

L Lin, G Pei, ZY Cao, S Liao - European Journal of Organic …, 2024 - Wiley Online Library
Sulfonyl fluorides have widespread applications in many fields, including organic synthesis,
chemical biology, drug discovery and materials science. In particular, in the past decade, a …

Radical Fluorosulfonyl Heteroarylation of Unactivated Alkenes with Quinoxalin-2(1H)-ones and Related N-Heterocycles

L Lin, P Wang, T Dong, GC Tsui, S Liao - Organic Letters, 2023 - ACS Publications
The incorporation of sulfonyl fluoride groups into molecules has been proved effective to
enhance their biological activities or introduce new functions. Herein, we report a transition …