Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

[HTML][HTML] CO 2-fixation into cyclic and polymeric carbonates: principles and applications

AJ Kamphuis, F Picchioni, PP Pescarmona - Green chemistry, 2019 - pubs.rsc.org
The reaction between carbon dioxide and epoxides is an attractive pathway for CO2-
utilisation as it can lead to the formation of two different, yet valuable, products: cyclic and …

Catalytic Strategies for the Cycloaddition of Pure, Diluted, and Waste CO2 to Epoxides under Ambient Conditions

RR Shaikh, S Pornpraprom, V D'Elia - Acs Catalysis, 2018 - ACS Publications
Cyclic organic carbonates represent a relevant class of chemicals that can be prepared from
CO2 by cycloaddition to epoxides. The application of efficient catalysts is crucial in allowing …

Organocatalyzed coupling of carbon dioxide with epoxides for the synthesis of cyclic carbonates: catalyst design and mechanistic studies

M Alves, B Grignard, R Méreau, C Jerome… - Catalysis Science & …, 2017 - pubs.rsc.org
The coupling of carbon dioxide (CO2) with epoxides with the formation of cyclic carbonates
is a highly attractive 100% atom economic reaction. It represents a greener and safer …

Tethering Dual Hydroxyls into Mesoporous Poly(ionic liquid)s for Chemical Fixation of CO2 at Ambient Conditions: A Combined Experimental and Theoretical Study

Z Guo, Q Jiang, Y Shi, J Li, X Yang, W Hou, Y Zhou… - ACS …, 2017 - ACS Publications
Vicinal dual hydroxyl functional mesoporous poly (ionic liquid) s with large surface area and
high ionic liquid (IL) content were synthesized through the copolymerization of epoxy …

CO2 Adducts of Phosphorus Ylides: Highly Active Organocatalysts for Carbon Dioxide Transformation

H Zhou, GX Wang, WZ Zhang, XB Lu - ACS Catalysis, 2015 - ACS Publications
A series of phosphorus ylide (P-ylide) CO2 adducts were synthesized and first used as
organocatalysts for CO2 transformation. Detailed studies on the cycloaddition reaction of …

Bio-based routes to synthesize cyclic carbonates and polyamines precursors of non-isocyanate polyurethanes: A review

M Ghasemlou, F Daver, EP Ivanova… - European Polymer …, 2019 - Elsevier
The synthesis of conventional polyurethanes (PUs) relies on isocyanate reactants as crucial
starting materials. Toxicity, water-sensitivity and phosgene-based synthesis of isocyanates …

Recent Developments in the Synthesis of Cyclic Carbonates from Epoxides and CO2

H Büttner, L Longwitz, J Steinbauer, C Wulf… - … of Carbon Dioxide, 2018 - Springer
The use of CO 2 as a C1 building block will be of essential importance in the future. In this
context the synthesis of cyclic carbonates from epoxides and CO 2 gained great attention …

Ascorbic Acid as a Bifunctional Hydrogen Bond Donor for the Synthesis of Cyclic Carbonates from CO2 under Ambient Conditions

S Arayachukiat, C Kongtes, A Barthel… - ACS Sustainable …, 2017 - ACS Publications
Readily available ascorbic acid was discovered as an environmentally benign hydrogen
bond donor for the synthesis of cyclic organic carbonates from CO2 and epoxides in the …

Regioselective halogenation of arenes and heterocycles in hexafluoroisopropanol

RJ Tang, T Milcent, B Crousse - The Journal of Organic Chemistry, 2018 - ACS Publications
Regioselective halogenation of arenes and heterocycles with N-halosuccinimides in
fluorinated alcohols is disclosed. Under mild condition reactions, a wide diversity of …