Cp2Ti (III) Cl and analogues as sustainable templates in organic synthesis

JM Botubol-Ares, MJ Durán-Peña, JR Hanson… - …, 2018 - thieme-connect.com
This short review aims to provide an overview of the use of Cp 2 Ti (III) Cl and other related
titanocene (III) species as coordinating reagents in template reactions in the selective …

The Proven Versatility of Cp2TiCl

AR Martínez, LP Morales, ED Ojeda… - The Journal of …, 2020 - ACS Publications
In the last two decades, titanocene monochloride has been postulated as a monoelectronic
transfer reagent capable of catalyzing an important variety of chemical transformations. In …

The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2015

JW Herndon - Coordination Chemistry Reviews, 2016 - Elsevier
This is a review of papers published in the year 2015 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond …

Chemoselective and stereoselective lithium carbenoid mediated cyclopropanation of acyclic allylic alcohols

MJ Durán-Peña, ME Flores-Giubi… - Organic & …, 2016 - pubs.rsc.org
The reaction of geraniol with different lithium carbenoids generated from n-BuLi and the
corresponding dihaloalkane has been evaluated. The reaction occurs in a chemo and …

Mild Epoxidation of Allylic Alcohols Catalyzed by Titanium (III) Complexes: Selectivity and Mechanism

JM Botubol-Ares, JR Hanson, R Hernández-Galán… - ACS …, 2017 - ACS Publications
A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary
allylic alcohols is described using tert-butyl hydroperoxide as oxidant and Ti (III) species …

Chemoselective syntheses of spirodihydrofuryl and spirocyclopropyl barbiturates via cascade reactions of barbiturate-based olefins and acetylacetone

X Yan, P Shao, X Song, C Zhang, C Lu… - Organic & Biomolecular …, 2019 - pubs.rsc.org
The Michael addition initiated ring closure reaction of barbiturate-based olefins and
acetylacetone with NBS has been explored. The efficient and chemoselective approach for …

Unexpected Mild Protection of Alcohols as 2‐O‐THF and 2‐O‐THP Ethers Catalysed by Cp2TiCl Reveal an Intriguing Role of the Solvent in the Single‐Electron …

MJ Durán‐Peña, JM Botubol‐Ares… - European Journal of …, 2015 - Wiley Online Library
A method for the conversion of primary, secondary and tertiary alcohols into the
corresponding THF ethers at room temperature and primary and secondary alcohols into the …

Ti‐Mediated Efficient Reductive Dehalogenation of Carbon–Halogen Bonds

JA González‐Delgado, C Prieto… - Asian Journal of …, 2016 - Wiley Online Library
A mild and efficient methodology for the reductive dehalogenation of carbon–halogen bonds
in both activated (allylic or benzylic) and non‐activated halides with excess TiIII is thoroughly …

Efficient O‐Acylation of Alcohols and Phenol Using Cp2TiCl as a Reaction Promoter

MJ Durán‐Peña, JM Botubol‐Ares… - European Journal of …, 2016 - Wiley Online Library
A method has been developed for the conversion of primary, secondary, and tertiary
alcohols, and phenol, into the corresponding esters at room temperature. The method uses …

Carbenes and nitrenes

E Gras, S Chassaing - … · 2017: An annual survey covering the …, 2020 - Wiley Online Library
Summary This Chapter Contains Sections titled: Reviews Generation, Structure, and
Reactivity Carbenes in Coordination Chemistry Carbene Complexes with Main Group …