Replacement strategies for non-green dipolar aprotic solvents
Dipolar aprotic solvents (DMSO, DMF, DMAc, NMP, etc.) have been widely used in organic
synthesis and pharmaceutical research because of their remarkable polarities and …
synthesis and pharmaceutical research because of their remarkable polarities and …
Sustainable flow approaches to active pharmaceutical ingredients
The adoption of flow conditions has been the object of growing attention from both academia
and industry. The shift from batch to continuous-flow technology is very stimulating from a …
and industry. The shift from batch to continuous-flow technology is very stimulating from a …
Quantitative sustainability assessment of flow chemistry–from simple metrics to holistic assessment
Flow chemistry has changed chemical process designs toward process intensification and is
generally considered as green methodology. In this connection, this perspective provides a …
generally considered as green methodology. In this connection, this perspective provides a …
Biomass waste-derived Pd–PiNe catalyst for the continuous-flow copper-free sonogashira reaction in a CPME–water azeotropic mixture
F Ferlin, F Valentini, D Sciosci… - ACS Sustainable …, 2021 - ACS Publications
Herein, we report on the development of a waste minimization/valorization methodology
applied to the representative benchmark Sonogashira cross-coupling reaction performed in …
applied to the representative benchmark Sonogashira cross-coupling reaction performed in …
Versatile applications of metallopolymers
The incorporation of metal complexes into polymers leads to functional materials; whereas,
the properties of polymers–easy processability, light weight or the adjustable molar mass …
the properties of polymers–easy processability, light weight or the adjustable molar mass …
Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis
Ionic liquids (ILs) have unique physicochemical properties that make them advantageous for
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …
Green solvent-processed organic electronic devices
Organic electronic FAB factories are hard-pressed due to the current regulatory
requirements which restrict (or ban) the use of hazardous solvents; on the other hand, toxic …
requirements which restrict (or ban) the use of hazardous solvents; on the other hand, toxic …
Removal and modification of directing groups used in metal-catalyzed C–H functionalization: the magical step of conversion into 'conventional'functional groups
RL Carvalho, RG Almeida, K Murali… - Organic & …, 2021 - pubs.rsc.org
Over the past few decades, regioselective catalytic C–H functionalization has provided an
attractive tool for unique retrosynthetic disconnections. The advancement of the directing …
attractive tool for unique retrosynthetic disconnections. The advancement of the directing …
Tailor-Made POLITAG-Pd0 Catalyst for the Low-Loading Mizoroki–Heck Reaction in γ-Valerolactone as a Safe Reaction Medium
F Valentini, L Carpisassi, A Comès… - ACS Sustainable …, 2022 - ACS Publications
In this contribution, we have reported our study on the fine-tuned design and synthesis of
new POLITAGs-Pd0 (POLymeric Ionic TAG) catalytic systems with the intention of defining …
new POLITAGs-Pd0 (POLymeric Ionic TAG) catalytic systems with the intention of defining …
Valorisation of urban waste to access low-cost heterogeneous palladium catalysts for cross-coupling reactions in biomass-derived γ-valerolactone
Herein we report a simple protocol for the valorisation of a common urban biowaste. The
lignocellulosic biomass obtained after the pre-treatment of pine needle urban waste is …
lignocellulosic biomass obtained after the pre-treatment of pine needle urban waste is …