Conspectus N-centered radicals are versatile reaction intermediates that can react with
various π systems to construct C–N bonds. Current methods for generating N-centered …

Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

There is a resurgence of interests in organic electrochemistry, which is generally accepted
as a green synthetic tool. In this context, many electrochemical methods have been …

Herein, we report a mild, operationally simple, multicatalytic method for the synthesis of β, γ-
unsaturated ketones via allylic acylation of alkenes. Specifically, the method combines N …

Frustrated radical pairs (FRPs) describe the phenomenon that two distinct radicals─ which
would otherwise annihilate each other to form a closed-shell covalent adduct─ can coexist …

A method for the regiodivergent aminooxygenation of aryl olefins under electrophotocatalytic
conditions is described. The procedure employs a trisaminocyclopropenium (TAC) ion …

An efficient Mn-catalyzed aerobic oxidative hydroxyazidation of olefins for synthesis of β-
azido alcohols has been developed. The aerobic oxidative generation of azido radical …

Advances in the field of transition-metal-free nitroxide-catalyzed aerobic oxidation processes
are covered in this critical review. Along with the relevant physical properties of nitroxides …

sp 3 C–H oxidation by remote H-radical shift with oxygen- and nitrogen-radicals: a recent
update - Organic & Biomolecular Chemistry (RSC Publishing) DOI:10.1039/C4OB00469H Royal …

A general visible light induced photoredox-catalyzed radical trifluoromethylation/cyclization
cascade of β-aryl-β, γ-unsaturated hydrazones and oximes is described. The protocol …