Direct conversion of methane to value-added chemicals over heterogeneous catalysts: challenges and prospects

P Schwach, X Pan, X Bao - Chemical reviews, 2017 - ACS Publications
The quest for an efficient process to convert methane efficiently to fuels and high value-
added chemicals such as olefins and aromatics is motivated by their increasing demands …

The direct catalytic oxidation of methane to methanol—a critical assessment

M Ravi, M Ranocchiari… - Angewandte Chemie …, 2017 - Wiley Online Library
Despite the large number of disparate approaches for the direct selective partial oxidation of
methane, none of them has translated into an industrial process. The oxidation of methane …

Catalysis for selected C1 chemistry

Y Liu, D Deng, X Bao - Chem, 2020 - cell.com
Catalytic conversion of one-carbon (C1) molecules, such as CO, CO 2, CH 4, and CH 3 OH,
into fuels and value-added chemicals is a vitally important process in the chemical industry …

Homogeneity of Supported Single‐Atom Active Sites Boosting the Selective Catalytic Transformations

Y Shi, Y Zhou, Y Lou, Z Chen, H Xiong… - Advanced …, 2022 - Wiley Online Library
Selective conversion of specific functional groups to desired products is highly important but
still challenging in industrial catalytic processes. The adsorption state of surface species is …

Room-temperature methane conversion by graphene-confined single iron atoms

X Cui, H Li, Y Wang, Y Hu, L Hua, H Li, X Han, Q Liu… - Chem, 2018 - cell.com
Direct conversion of methane to high-value-added chemicals is a major challenge in
catalysis, which usually requires high-energy input to overcome the reaction barrier. We …

Undirected, homogeneous C–H bond functionalization: challenges and opportunities

JF Hartwig, MA Larsen - ACS central science, 2016 - ACS Publications
The functionalization of C–H bonds has created new approaches to preparing organic
molecules by enabling new strategic “disconnections” during the planning of a synthetic …

Robust catalysis on 2D materials encapsulating metals: concept, application, and perspective

J Deng, D Deng, X Bao - Advanced Materials, 2017 - Wiley Online Library
Great endeavors are undertaken to search for low‐cost, rich‐reserve, and highly efficient
alternatives to replace precious‐metal catalysts, in order to cut costs and improve the …

Alkane oxidation: methane monooxygenases, related enzymes, and their biomimetics

VCC Wang, S Maji, PPY Chen, HK Lee, SSF Yu… - Chemical …, 2017 - ACS Publications
Methane monooxygenases (MMOs) mediate the facile conversion of methane into methanol
in methanotrophic bacteria with high efficiency under ambient conditions. Because the …

Copper active sites in biology

EI Solomon, DE Heppner, EM Johnston… - Chemical …, 2014 - ACS Publications
On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …

Direct conversion of methane to methanol under mild conditions over Cu-zeolites and beyond

P Tomkins, M Ranocchiari… - Accounts of chemical …, 2017 - ACS Publications
Conspectus In the recent years methane has become increasingly abundant. However,
transportation costs are high and methane recovered as side product is often flared rather …