Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

The addition of heteroatom-hydrogen (Het-H) bonds across the carbon-carbon triple bond,
catalyzed by transition-metal complexes, is one of the most interesting and intriguing …

The carbon− nitrogen bond of carboxamides is extremely stable under most conditions. The
present study reveals that simple zirconium− and hafnium− amido complexes are highly …

This contribution reports the efficient and regiospecific Cp '2LnCH (SiMe3) 2 (Ln= La, Nd,
Sm, Lu; Cp '= η5-Me5C5)-and Me2SiCp ''2LnCH (SiMe3) 2 (Ln= Nd, Sm; Cp ''= η5-Me4C5) …

Lanthanide metallocenes catalyze the regiospecific intermolecular addition of primary
amines to acetylenic, olefinic, and diene substrates at rates which are∼ 1/1000 those of the …

In this Forum Article, we discuss the use of redox-active pincer-type ligands to enable
multielectron reactivity, specifically nitrene group transfer, at the electron-poor metals …

Turning a disadvantage to an advantage: The rather disappointing reactivity of the metal–
nitrogen bond in comparison to the metal–carbon bond resulted in the neglect of …

Monoimido derivatives of uranium (IV) have been prepared by both metathesis and direct
protonation routes. The reaction of lithium anilide with (^-CsMeshUMeCl in the presence of …

Addition of 2.0 equiv of Na (silox) to TiCl4 (THF) 2 afforded (silox) 2TiCl2 (1), which yielded
(silox) 2 (tBu3SiNH) TiCl (2-Cl) upon treatment with tBu3SiNLi. Grignard or alkyllithium …

In this critical review we summarize the latest results obtained during the last decade
concerning the catalytic activities of organoactinide complexes. We begin with a brief …