Recent advances in polyoxometalate-catalyzed reactions

SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Hybrid polyoxometalate materials for photo (electro-) chemical applications

JJ Walsh, AM Bond, RJ Forster, TE Keyes - Coordination Chemistry …, 2016 - Elsevier
Polyoxometalate (POM) based supramolecular assemblies have received significant
attention over recent years because of their unique and diverse redox and photochemical …

Heterogenization of heteropoly compounds: a review of their structure and synthesis

E Rafiee, S Eavani - RSC advances, 2016 - pubs.rsc.org
The application of catalysis to reduced toxicity systems and benign and renewable energy
systems is a central focus area for green chemistry research. It is possible to prepare …

Noncovalent dualism in perylene-diimide-based keggin anion complexes: theoretical and experimental studies

VG Popova, LV Kulik, RI Samoilova, DV Stass… - Inorganic …, 2023 - ACS Publications
We report the synthesis and comprehensive characterization of organic–inorganic hybrid
salts formed by bis-cationic N, N′-bis (2-(trimethylammonium) ethylene) perylene-3, 4, 9 …

Applications of inorganic‐organic hybrid architectures based on polyoxometalates in catalyzed and photocatalyzed chemical transformations

N Lotfian, MM Heravi, M Mirzaei… - Applied Organometallic …, 2019 - Wiley Online Library
The scope of this article is to reveal the fruitful combination of POM species with metal
coordination complexes, leading to the construction of several efficient multifunctional …

Recent advances in applications of POMs and their hybrids in catalysis

S Sadjadi, M M. Heravi - Current Organic Chemistry, 2016 - benthamdirect.com
Polyoxometalates (POMs) and their hybrid systems are green and efficient catalysts which
have found a wide range of application, due to their outstanding properties such as high …

Photochemical reduction of carbon dioxide coupled with water oxidation using various soft-oxometalate (SOM) based catalytic systems

S Das, S Biswas, T Balaraju, S Barman… - Journal of Materials …, 2016 - pubs.rsc.org
Simultaneous CO2 reduction and water oxidation as a coupled process is an important
challenge in the quest of clean energy production. Herein, we report a metal oxide based …

Polyoxometalate-based organic–inorganic hybrid compounds containing transition metal mixed-organic-ligand complexes of N-containing and pyridinecarboxylate …

DC Zhao, YY Hu, H Ding, HY Guo, XB Cui… - Dalton …, 2015 - pubs.rsc.org
Five new organic–inorganic hybrid compounds based on the Keggin-type polyoxoanion
[SiW12O40] 4−, namely [Cu3 (2, 2′-bpy) 3 (inic)(μ2-OH)(H2O)][SiW12O40]· 2H2O (1),[Cu6 …

Polyoxometalates as heterogeneous catalysts for organic reactions

E Rafiee, S Eavani - Current Organic Chemistry, 2017 - ingentaconnect.com
Over the past decade, polyoxometalates (POMs) have attracted extensive attention as
homogeneous and heterogeneous catalysts or nanocatalysts for organic transformation. The …

Selective Photocatalytic Carbon Dioxide Reduction by a Reduced Molybdenum‐Based Polyoxometalate Catalyst

S Barman, SS Sreejith, S Garai… - …, 2019 - Wiley Online Library
Currently, photochemical carbon dioxide reduction is a most sought‐after process as it
involves the simultaneous removal of greenhouse CO2 gas and the production of useful …