Heterolytic Dissociation of H2 in Heterogeneous Catalysis
DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …
Reversible Pd Catalysts Supported on Hierarchical Titanate Nanosheets for an N-Methylindole-Based Liquid Organic Hydrogen Carrier
Reversible hydrogenation and dehydrogenation processes were investigated in a liquid
organic hydrogen carrier (LOHC) system by employing a single-catalyst approach. Key …
organic hydrogen carrier (LOHC) system by employing a single-catalyst approach. Key …
Design of gold catalysts for activation of H 2 and H-donor molecules: transfer hydrogenation and CO 2 hydrogenation
Catalytic activation of dihydrogen (H2) on metal surfaces allowed the development of very
important industrial hydrogenation processes and plays also an important role in the context …
important industrial hydrogenation processes and plays also an important role in the context …
Theoretical Insights into H2 Activation over Anatase TiO2 Supported Metal Adatoms
H2 activation is fundamental in catalysis. Single-atom catalysts (SACs) can be highly
selective hydrogenation catalysts due to their tunable geometric and electronic properties. In …
selective hydrogenation catalysts due to their tunable geometric and electronic properties. In …
[HTML][HTML] Heterolytic dissociation of H2 and bond activation: Spotting new opportunities from a unified view
Y Jing, Y Wang - Chem Catalysis, 2023 - cell.com
Catalytic hydrogenation/hydrogenolysis always involves the dissociation of H 2 and the
activation of substrate. H 2 can be dissociated via homolytic and heterolytic pathways. The …
activation of substrate. H 2 can be dissociated via homolytic and heterolytic pathways. The …
Potassium as the best alkali metal promoter in boosting the hydrogenation activity of Ru/MgO for aromatic LOHC molecules by facilitated heterolytic H2 adsorption
Alkali metals (AM) are frequently used as promoters in a number of reactions. In aromatic
hydrogenation over Ru/MgO, their basicity may promote heterolytic H 2 adsorption, thereby …
hydrogenation over Ru/MgO, their basicity may promote heterolytic H 2 adsorption, thereby …
Engineering a Ni1Fe1–ZnO Interface to Boost Selective Hydrogenation of Methyl Stearate to Octadecanol
T Zhang, H Yan, Z Liu, W Zhan, H Yu, Y Liao, Y Liu… - ACS …, 2022 - ACS Publications
Tailoring the hydrodeoxygenation capacity via construction of metal–support interfaces is
still a significant challenge for hydrogenation of oxygenated substrates. Herein, we boosted …
still a significant challenge for hydrogenation of oxygenated substrates. Herein, we boosted …
Electronic vs. Geometric effects of Al2O3-supported Ru species on the adsorption of H2 and substrate for aromatic LOHC hydrogenation
The intrinsic rate of aromatic hydrogenation is tuned by electronic and geometric characters
of active metals. Herein, Ru/Al 2 O 3 catalysts were prepared by varying the Ru loading from …
of active metals. Herein, Ru/Al 2 O 3 catalysts were prepared by varying the Ru loading from …
Sustainable Production of Chemicals via Hydrotreating of CO2 and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts
E Naranov - ChemCatChem, 2024 - Wiley Online Library
The noble metals are widely used in heterogeneous catalysis and automobile industry. The
limited natural sources and high cost of noble metals dictates improving the efficiency of …
limited natural sources and high cost of noble metals dictates improving the efficiency of …
Advanced heterolytic H2 adsorption of K-added Ru/MgO catalysts for accelerating hydrogen storage into aromatic benzyltoluenes
Herein, we report a highly active K-added Ru/MgO catalyst for hydrogen storage into
aromatic benzyltoluenes at low temperatures to advance liquid organic hydrogen carrier …
aromatic benzyltoluenes at low temperatures to advance liquid organic hydrogen carrier …