Recent development in catalytic application of transition metal complexes having an M–E
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …

The stabilization and isolation of highly reactive species has long been the subject of
chemical research. This review will focus on a large and important class of reactive species …

In 1963 Shriver reported a metal-boron dative bond in a complex formulated as [(η5-C5H5)
2WH2 (BF3)]. 33 However, these findings were refuted around 30 years later when differing …

Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

Despite the widespread use of organoborane reagents in organic synthesis and catalysis, a
major challenge still remains: very few boron-centered nucleophiles exist for the direct …

Efficient synthesis and catalysis of a series of palladium complexes having a group 13
metalloligand (Al, Ga, In) are reported utilizing 6, 6 ″-bis (phosphino) terpyridine as a new …

Cu-catalyzed methods for site-selective hydroboration of terminal alkynes, where the
internal or α-vinylboronate is generated predominantly (up to> 98%) are presented …

New approaches toward the generation of late first-row metal catalysts that efficiently
facilitate two-electron reductive transformations (eg, hydrogenation) more typical of noble …

The iridium-catalyzed borylation of mono-and disubstituted arenes and heteroarenes has
been studied with density functional theory. The distortion/interaction model was employed …

Conspectus Aromaticity, one of the most fundamental concepts in chemistry, has attracted
considerable attention from both theoreticians and experimentalists. Much effort on …