In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Conspectus Activation of inert chemical bonds, such as C–H, C–O, C–C, and so on, is a very
important area, to which has been drawn much attention by chemists for a long time and …

Metal-catalyzed cross-couplings represent one of the most important reaction platforms in
modern synthetic chemistry (Figure 1 A). 1 Although the field enjoys a rich history, there …

Transition metal-catalyzed cross-coupling reactions of organic electrophiles and
organometallic reagents have emerged as a tremendously powerful synthetic tool, and the …

Since their development in the 1970s, cross-coupling reactions catalyzed by transition
metals have become one of the most important tools for constructing both carbon− carbon …

The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Aryl halides are very useful electrophiles for synthesizing various substituted aromatic
compounds via metal-catalyzed cross-coupling reactions. Because of the high cost …

The synthesis of all-carbon tetrasubstituted olefins under mild reaction conditions is
challenging because of the inevitable issues including significant steric hindrance and the …