Electrochemical Reactors Enable Divergent Site Selectivity in the C−H Carboxylation of N‐Heteroarenes

PZ Wang, WJ Xiao, JR Chen - … Chemie International Edition, 2023 - Wiley Online Library
Catalytic and switchable C− H functionalization of N‐heteroarenes under easily tunable
conditions is a robust but challenging tool for the construction of biologically relevant …

Recent Advances in Electrochemical Carboxylation with CO2

GQ Sun, LL Liao, CK Ran, JH Ye… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Carbon dioxide (CO2) is recognized as a greenhouse gas and a common
waste product. Simultaneously, it serves as an advantageous and commercially available …

Electrochemical reactor dictates site selectivity in N-heteroarene carboxylations

GQ Sun, P Yu, W Zhang, W Zhang, Y Wang, LL Liao… - Nature, 2023 - nature.com
Pyridines and related N-heteroarenes are commonly found in pharmaceuticals,
agrochemicals and other biologically active compounds,. Site-selective C–H …

Visible-light-driven synthesis of N-heteroaromatic carboxylic acids by thiolate-catalysed carboxylation of C(sp²)–H bonds using CO2

YX Jiang, LL Liao, TY Gao, WH Xu, W Zhang, L Song… - Nature …, 2024 - nature.com
Catalytic carboxylation of C–H bonds using CO2 is a sustainable and economic strategy to
produce valuable carboxylic acids. However, this process presents challenges due to the …

[HTML][HTML] Electrochemical N-heteroarene carboxylation: Reactor-dependent site selectivity

L Li, N Fu - Chem, 2023 - Elsevier
Selectivity is typically achieved through chemical approaches. Recently in Nature, Yu, Lin,
and co-workers disclosed an electrochemical carboxylation of N-heteroarenes with site …

Electrochemical behavior of tetrafluoro-p-benzoquinone at the presence of carbon dioxide: Experimental and theoretical studies

M Namazian, HR Zare, H Yousofian-Varzaneh - Electrochimica Acta, 2016 - Elsevier
The electrochemical behavior of p-benzoquinone, BQ, and tetrafluoro-p-benzoquinone,
TFBQ, in the DMF solvent in the absence and the presence of carbon dioxide, CO 2, were …

Synthesis and investigation of tetraphenyltetrabenzoporphyrins for electrocatalytic reduction of carbon dioxide

DH Apaydin, E Portenkirchner, P Jintanalert… - Sustainable Energy & …, 2018 - pubs.rsc.org
We report the synthesis and electrochemical properties of freebase
tetraphenyltetrabenzoporphyrin and its complexes of Zn (II), Co (II), Ni (II), Cu (II) and Sn (IV) …

New insight into electrochemical behavior of copper complexes and their applications as bifunctional electrocatalysts for CO2 activation

H Khoshro, HR Zare, R Vafazadeh - Journal of CO2 Utilization, 2015 - Elsevier
The electrochemical behaviors of two copper Schiff base complexes,[N, N′-bis (2-R-phenyl-
salicylidenaminato) Cu (II)] complex,(CuL 2–Me for R= Me, and CuL 2–Cl for R= Cl), and [N …

Thermal behaviour of nitrogen oxides relevant to oxidative denitrogenation

S Mirshamsi, Y Yan, S Kamal, AA Yasemi… - The Journal of Chemical …, 2019 - Elsevier
Nitrogen compounds in crude oil are known to cause several problems during refining
including catalyst deactivation and gum formation. Industrially, nitrogen is removed by hydro …

Excellent electrocatalytic activity of benzil for direct reduction of CO2 as well as indirect reduction of pyridine: A kinetic view of the electrocarboxylation process

K Ghobadi, HR Zare, H Khoshro, AA Jafari - Journal of Energy Chemistry, 2017 - Elsevier
Abstract Benzil, 1, 2-diphenylethane-1, 2-dione, was used as an excellent electrocatalyst for
reduction of carbon dioxide, CO 2. The reduction overpotential of CO 2 was reduced about …