Fluorinated gases (F-gases) are routinely employed as refrigerants, blowing agents, and
electrical insulators. These volatile compounds are potent greenhouse gases and …

Fluorinated compounds attracted remarkable interest in recent decades. 1 Unique complex
of physicochemical and biological properties provided by incorporation of fluorine or …

Trifluoromethylphosphines represent a rare kind of phosphine with unique electronic
withdrawing properties, which lead to some distinctive reactivities. The reported TFMPhos …

This review presents a comprehensive assessment of the synthetic utility of n-perfluoroalkyl
iodides (RFI, CnF2n+ 1-I, where n= 2–14) in the published literature from 2000 through …

Organophosphorus compounds are widely used as ligands in metal catalysts. Specifically,
perfluoroalkylated phosphines are gaining attention because of their fluorous affinity.[1] In …

Organophosphorus Chemistry provides a comprehensive annual review of the literature.
Coverage includes phosphines and their chalcogenides, phosphonium salts, low …

Controlling the reactivity of transition metal complexes by positioning non-innocent
functionalities around the catalytic pocket is a concept that has led to significant advances in …

This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

The chemistry of phosphorus (III) ligands, which are of key importance in coordination
chemistry, organometallic chemistry and catalysis, is dominated by relatively electron‐rich …

Reaction of a series of HFCs with a main group reagent containing a Mg–Mg bond results in
defluorination to form the corresponding magnesium fluoride complex. In the case of 1, 1, 1 …