The anionic Fries rearrangement: a convenient route to ortho-functionalized aromatics

M Korb, H Lang - Chemical Society Reviews, 2019 - pubs.rsc.org
The ortho-directed lithiation of aromatic carbamates and carbonates causes a migration of
the substituent from the pendant O group to the adjacent C atom of the aromatic scaffold …

Negishi coupling in the synthesis of advanced electronic, optical, electrochemical, and magnetic materials

S Huo, R Mroz, J Carroll - Organic Chemistry Frontiers, 2015 - pubs.rsc.org
Negishi coupling is one of the most important modern organic synthetic methods for
selective C–C bond formation, and has been extensively applied in the synthesis of organic …

Electronic coupling in 1, 2, 3-triazole bridged ferrocenes and its impact on reactive oxygen species generation and deleterious activity in cancer cells

P Biegański, E Kovalski, N Israel, E Dmitrieva… - Inorganic …, 2022 - ACS Publications
Mixed-valence (MV) binuclear ferrocenyl compounds have long been studied as models for
testing theories of electron transfer and in attempts to design molecular-scale electronic …

Planar-chiral 1, 1′-diaminoferrocenes

R Guthardt, J Blanckenberg, C Bruhn… - Chemical …, 2021 - pubs.rsc.org
Planar-chiral homologues of 1, 1′-diaminoferrocene, which bear a single additional
substituent adjacent to one of the amino groups, are prepared as racemic mixtures in a few …

Rational Control of Conformational Distributions and Mixed‐Valence Characteristics in Diruthenium Complexes

JBG Gluyas, S Gückel, M Kaupp… - Chemistry–A European …, 2016 - Wiley Online Library
The electronic characteristics of mixed‐valence complexes are often inferred from the shape
of the inter‐valence charge transfer (IVCT) band, which usually falls in the near infrared …

Ferrocenyl-based di-and trinuclear lanthanide complexes: solid state structures,(spectro) electrochemical and DFT studies

A Khalladi, E Kovalski, MA Abdulmalic, T Rüffer… - Dalton …, 2023 - pubs.rsc.org
Dinuclear and trinuclear ferrocenylcarboxylato-bridged lanthanide complexes of type [Ln
(μO: κ2OO′-O2CFc)(O2CFc) 2 (H2O)(dmf)] 2·(dmf) 2 (Ln= Sm (2), Eu (3), Gd (4), Tb (5); Fc …

Electronic Properties of Mono‐Substituted Tetraferrocenyl Porphyrins in Solution and on a Gold Surface: Assessment of the Influencing Factors for …

A Vecchi, NR Erickson, JR Sabin… - … A European Journal, 2015 - Wiley Online Library
Two unsymmetric meso‐tetraferrocenyl‐containing porphyrins of general formula Fc3
(FcCOR) Por (Fc= ferrocenyl, R= CH3 or (CH2) 5Br, Por= porphyrin) were prepared and …

Influence of P‐Bonded Bulky Substituents on Electronic Interactions in Ferrocenyl‐Substituted Phospholes

D Miesel, A Hildebrandt, M Korb… - … A European Journal, 2015 - Wiley Online Library
Diferrocenyl‐1‐Ar‐1H‐phospholes 3 a–e (Ar= phenyl (a), ferrocenyl (b), mesityl (c), 2, 4, 6‐
triphenylphenyl (d), and 2, 4, 6‐tri‐tert‐butylphenyl (e)) have been prepared by reactions of …

Electronic modification of redox active ferrocenyl termini and their influence on the electrontransfer properties of 2, 5-diferrocenyl-N-phenyl-1H-pyrroles

SW Lehrich, A Hildebrandt, M Korb, H Lang - Journal of Organometallic …, 2015 - Elsevier
Abstract A series of 2, 5-diferrocenyl-N-phenyl-1H-pyrroles of type 2, 5-Fc 2-c C 4 H 2 NPh
(Fc= Fe (η 5-C 5 H 4)(η 5-C 5 H 4 R); 3a, R= c C 4 H 7 O 2; 3b, H; 3c, 3, 5-(CF 3) 2-C 6 H 3) …

Transition-Metal Carbonyl Complexes of 2,5-Diferrocenyl-1-phenyl-1H-phosphole

D Miesel, A Hildebrandt, M Korb… - …, 2015 - ACS Publications
Pentacarbonyl (2, 5-diferrocenyl-1-phenyl-1 H-phosphole) metal complexes 3a–c (3a, M=
Cr; 3b, M= Mo; 3c, M= W) have successfully been synthesized by the reaction of 2, 5 …