Conspectus Molecules and materials with easily tunable electronic structures and properties
are at the forefront of contemporary research. π-Conjugation is fundamental in organic …

Since the beginning of the seventies, organophosphorus chemistry has been completely
rejuvenated by the discovery of stable derivatives in which phosphorus has the coordination …

Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [LnM P
R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of …

Of the low-valent organophosphorus compounds phosphinidenes occupy a special place. In
'free'phosphinidenes the phosphorus atom carries a single substituent. Such species prefer …

Abstract Reaction of [U (TrenTIPS)(THF)][BPh4](1; TrenTIPS= N {CH2CH2NSi (iPr) 3} 3) with
NaPH2 afforded the novel f‐block terminal parent phosphide complex [U …

The N‐heterocyclic carbene–phosphinidene adduct IPr PSiMe3 is introduced as a synthon
for the preparation of terminal carbene–phosphinidyne transition metal complexes of the …

Die gesamte phosphororganische Chemie wurde mit Beginn der siebziger Jahre infolge der
Entdeckung stabiler phosphororganischer Derivate mit Koordinationszahlen des Phosphors …

The synthesis, structure, and reactivity of a base-free terminal actinide phosphinidene
metallocene have been comprehensively studied. The salt metathesis reaction of the …

α-Hydrogen abstraction and α-hydrogen migration reactions yield novel titanium (IV)
complexes bearing terminal phosphinidene ligands. Via an α-H migration reaction, the …

The first stable base‐free terminal uranium phosphinidene metallocene is presented; and its
structure and reactivity have been studied in detail and compared to that of the …