We report a photoredox system comprising sodium iodide, triphenyl phosphine, and N, N,
N′, N′-tetramethylethylenediamine (TMEDA) that can form a self-assembled tetrameric …

We report an organophotoredox-catalyzed stereoselective allylic arylation of MBH acetates
with a palette of diaryliodonium triflates (DAIRs) to provide the corresponding trisubstituted …

Pnictogen bonding (PnB) has gained recognition as an appealing strategy for constructing
novel architectures and unlocking new properties. Within the synthetic community, the …

Diethyl acetamidomalonate (DEAM) has been widely used for the synthesis of α-amino
acids via C-alkylation under basic conditions followed by hydrolysis/decarboxylation. In …

Arylation of amino‐, diamino‐and triaminophosphines with aryl (mesityl) iodonium triflates
under blue light irradiation followed by oxidative P− N bond cleavage in the in situ …

The interaction of a diphenyliodonium salt with trivalent phosphorus compounds and the
relevance of these interactions in visible light induced reactions were studied using {1H …

Visible‐light‐activated organic reactions unlock novel avenues for complex molecular
transformations, impossible under standard “thermal” conditions, which makes them …

We demonstrate (1) detectable halogen bonding is not critical for enabling light-driven
radical generation from diaryliodonium salts and (2) radicals generated by this route can be …

In recent times, diaryliodonium reagents (DAIRs) have witnessed a resurgence as arylating
reagents, especially under photoinduced conditions. However, reactions proceeding …

We disclose a photoredox-catalyzed arylative radical cascade between N′-arylidene-N-
acryloylhydrazides and diaryliodonium reagents to obtain the corresponding benzylated …