Gas-phase ion chemistry of [B12X12] 2−(X= F, Cl, Br, I, CN) A brief review of twelve years of researching twelve− vertexed dianions and their fragments
J Warneke - International Journal of Mass Spectrometry, 2023 - Elsevier
The closo-dodecaborate dianions [B 12 X 12] 2−(X= halogen, CN) have been recognized in
recent years for their outstanding physical and chemical properties. Gas-phase ion …
recent years for their outstanding physical and chemical properties. Gas-phase ion …
Chemistry of three-dimensional icosahedral boron clusters anions: closo-dodecaborate (2-)[B12H12] 2-and carba-closo-dodecaborate (-)[CB11H12]-
L Wang, Y Jiang, S Duttwyler, F Lin, Y Zhang - Coordination Chemistry …, 2024 - Elsevier
Significant strides have been made in synthetic chemistry concerning icosahedral boron
clusters over the past decades, resulting in a proliferation of applications across various …
clusters over the past decades, resulting in a proliferation of applications across various …
Electrochemical Synthesis of Triphenylphosphine Coinage Metal Complexes stabilized by closo‐Dodecaborates [B12X12]2− (X=H, F, Cl, Br, I)
RM Exner, C Jenne, B Wegener - Zeitschrift für anorganische …, 2021 - Wiley Online Library
The synthesis of salts of reactive cations and weakly coordinating anions is of great interest
to the development of catalysts, because the weak electrostatic interaction between the two …
to the development of catalysts, because the weak electrostatic interaction between the two …
Derivatization of Undecahalogenated closo-Dodecaborates [B12X11NH3]− (X = F–I): Attaching Isocyanate, Amidinium, and Formamide Functionalities
C Jenne, H Knorke, MC Nierstenhöfer… - Inorganic …, 2024 - ACS Publications
Halogenated closo-dodecaborates are very robust and versatile weakly coordinating anions
for numerous applications. The introduction of additional substituents, eg, pseudohalides …
for numerous applications. The introduction of additional substituents, eg, pseudohalides …
Activation of Small Molecules by Modified Dodecaborate Anions
Two of the basic requirements of a good catalyst are that molecules be bound to it with
energies intermediate between physisorption and chemisorption and be simultaneously …
energies intermediate between physisorption and chemisorption and be simultaneously …
Probing the Electronic Structure of [B10H10]2– Dianion Encapsulated by an Octamethylcalix[4]pyrrole Molecule
Despite being an important closo-borate in condensed phase boron chemistry, isolated
[B10H10] 2–is electronically unstable and has never been detected in the gas phase …
[B10H10] 2–is electronically unstable and has never been detected in the gas phase …
Measuring Electronic Structure of Multiply Charged Anions to Understand Their Chemistry: A Case Study on Gaseous Polyhedral closo-Borate Dianions
Research on multiply charged anions (MCAs) in the gas phase has been intensively
performed during the past decades, mainly to understand fundamental molecular physics …
performed during the past decades, mainly to understand fundamental molecular physics …
Understanding the Electronic Structure and Stability of BnXn0/2– (n = 4, 6; X = H, F, Cl, Br, I, At, Ts) Clusters†
RY Wang, JX Zhang, XL Jiang, N Ma… - Chinese Journal of …, 2021 - Wiley Online Library
Main observation and conclusion Borane clusters and their derivatives have attracted
extensive attention in inorganic chemistry due to their fascinating multi‐center bonding …
extensive attention in inorganic chemistry due to their fascinating multi‐center bonding …
[引用][C] Main group metal coordination chemistry
CE Housecroft, EC Constable - 2023 - Elsevier