Chiroptical properties of symmetric double, triple, and multiple helicenes

T Mori - Chemical Reviews, 2021 - ACS Publications
Helicenes have attracted considerable attention due to their inherent helical chirality and
extended π-conjugation. Recently, rapid progress has been witnessed in the preparation of …

Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

[HTML][HTML] Synthesis of a Möbius carbon nanobelt

Y Segawa, T Watanabe, K Yamanoue, M Kuwayama… - Nature …, 2022 - nature.com
Technologies for the creation of topological carbon nanostructures have greatly advanced
synthetic organic chemistry and materials science. Although simple molecular nanocarbons …

Synthesis of π-conjugated chiral organoborane macrocycles with blue to near-infrared emissions and the diradical character of cations

F Zhao, J Zhao, H Liu, Y Wang, J Duan… - Journal of the …, 2023 - ACS Publications
Highly emissive π-conjugated macrocycles with tunable circularly polarized luminescence
(CPL) have sparked theoretical and synthetic interests in recent years. Herein, we report a …

Fluorescent Origin and Chiral Nature of MöBius Carbon Nanobelts

B Sun, X Ren, J Li, J Chen - The Journal of Physical Chemistry C, 2023 - ACS Publications
In this paper, we theoretically explore the physical mechanism of the fluorescent origin and
chiral nature of Möbius carbon nanobelts. The electron–hole recombination is promoted by …

The ascent of alkyne metathesis to strategy-level status

A Fürstner - Journal of the American Chemical Society, 2021 - ACS Publications
For numerous enabling features and strategic virtues, contemporary alkyne metathesis is
increasingly recognized as a formidable synthetic tool. Central to this development was the …

[HTML][HTML] Lemniscular carbon nanohoops with contiguous conjugation from planar chiral [2.2] paracyclophane: influence of the regioselective synthesis on topological …

J He, MH Yu, Z Lian, YQ Fan, SZ Guo, XN Li… - Chemical …, 2023 - pubs.rsc.org
We report herein the regioselective synthesis of all-carbon lemniscular nanohoops bis-po-
CC and bis-pm-TC by the rational control of ring closures at the different positions of planar …

A Fused [5] Helicene Dimer with a Figure‐Eight Topology: Synthesis, Chiral Resolution, and Electronic Properties

Q Zhou, X Hou, J Wang, Y Ni, W Fan, Z Li… - Angewandte …, 2023 - Wiley Online Library
Chiral shape‐persistent molecular nanocarbons are promising chiroptical materials; their
synthesis, however, remains a big challenge. Herein, we report the facile synthesis and …

Circularly polarized luminescence in a Möbius helicene carbon nanohoop

J Malinčík, S Gaikwad, JP Mora‐Fuentes… - Angewandte Chemie …, 2022 - Wiley Online Library
We present the first helicene carbon nanoohop that integrates a [6] helicene into [7]
cycloparaphenylene. The [6] helicene endows the helicene carbon nanohoop with …

Facile Synthesis and Chiral Resolution of Expanded Helicenes with up to 35 cata‐Fused Benzene Rings**

GF Huo, TM Fukunaga, X Hou, Y Han… - Angewandte Chemie …, 2023 - Wiley Online Library
Expanded helicenes are expected to show enhanced chiroptical properties as compared to
the classical helicenes but the synthesis is very challenging. Herein, we report the facile …